Switching of spin-state complexes induced by the interaction of a laser beam with their host matrix
Langue
en
Article de revue
Ce document a été publié dans
Applied Physics Letters. 2013-09-30, vol. 103, n° 14, p. 143304 (1-5)
American Institute of Physics
Résumé en anglais
We demonstrate that the interaction of a CO2 laser with a host matrix, in which spin-crossover compounds are diluted, makes it possible to induce a low-spin-to-high-spin transition. The phenomenon is demonstrated for two ...Lire la suite >
We demonstrate that the interaction of a CO2 laser with a host matrix, in which spin-crossover compounds are diluted, makes it possible to induce a low-spin-to-high-spin transition. The phenomenon is demonstrated for two different compounds diluted in a commercial polymer. The photo-induced transition is due to laser-induced heating of the host-matrix, which results in a localized modification of the properties of the sample. This phenomenon is reversible, and its kinetics are well accounted for by a simple model. This process makes it possible to write optical information at a high speed and to erase it in such materials.< Réduire
Project ANR
Vers une génération de Gel-Coats Intelligents : thermo- et/ou photosensibles
Origine
Importé de halUnités de recherche