Continuous coflow synthesis of hybrid palladium nanocrystals as catalysts for borylation reaction.
Langue
en
Article de revue
Ce document a été publié dans
Nanoscale. 2013, vol. 5, n° 24, p. 12425-12431
Royal Society of Chemistry
Résumé en anglais
The combination of highly active Pd nanocrystal (NC) types with tailored surface properties (various ligands) - e.g. organic-inorganic hybrid NCs - as catalysts opens avenues towards new synthetic pathways, implying a ...Lire la suite >
The combination of highly active Pd nanocrystal (NC) types with tailored surface properties (various ligands) - e.g. organic-inorganic hybrid NCs - as catalysts opens avenues towards new synthetic pathways, implying a faster practical alternative for adjusting and screening the reaction conditions. Pd@dppf and Pd@PCy3 NCs have been successfully prepared via a continuous supercritical fluid assisted coflow route with promising results as catalysts in borylation reaction. It has been found that the ligands not only influence the catalytic properties of the systems, but also contribute to Pd metal core characteristics (size, shape and time stability).< Réduire
Mots clés en anglais
Hybrid materials
Nanoparticles
Palladium
Chemical synthesis
Origine
Importé de halUnités de recherche