The system will be going down for regular maintenance. Please save your work and logout.

Show simple item record

hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSCHMIDT, Whitney
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorBERTHELOT, Romain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorÉTIENNE, Laetitia
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorWATTIAUX, Alain
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSUBRAMANIAN, Mass A.
dc.date.issued2014
dc.identifier.issn0025-5408
dc.description.abstractEnA new compound Na3LiFeSbO6 has been synthesized by conventional solid state methods and investigated using X-ray diffraction, DC magnetic susceptibility, 57Fe Mössbauer spectroscopy and optical measurements. This compound crystallizes in a monoclinic unit cell and is related to a family of honeycomb ordered layered oxide materials where Na+ fills octahedral interlayer sites between Li1/3Fe1/3Sb1/3O2 slabs of edge sharing octahedra. Each SbO6 octahedron is surrounded by LiO6 and FeO6 octahedra creating a honeycomb arrangement within the slabs. Powder X-ray diffraction indicates the presence of stacking faults. This compound exhibits Curie-Weiss behavior at high temperatures and the effective magnetic moment verifies the presence of high spin Fe3+. The 57Fe Mössbauer spectroscopy confirms Fe3+ in an octahedral position and indicates disorder in the arrangement of LiO6 and FeO6 octahedra in the Li1/3Fe1/3Sb1/3O2 slabs.
dc.language.isoen
dc.publisherElsevier
dc.subject.enLayered compounds
dc.subject.enMagnetic properties
dc.subject.enOptical properties
dc.subject.enMössbauer spectroscopy
dc.subject.enX-ray diffraction
dc.title.enSynthesis and characterization of O3-Na3LiFeSbO6: A new honeycomb ordered layered oxide
dc.typeArticle de revue
dc.identifier.doi10.1016/j.materresbull.2013.10.049
dc.subject.halChimie/Matériaux
bordeaux.journalMaterials Research Bulletin
bordeaux.page292-296
bordeaux.volume50
bordeaux.peerReviewedoui
hal.identifierhal-00956475
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00956475v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Research%20Bulletin&rft.date=2014&rft.volume=50&rft.spage=292-296&rft.epage=292-296&rft.eissn=0025-5408&rft.issn=0025-5408&rft.au=SCHMIDT,%20Whitney&BERTHELOT,%20Romain&%C3%89TIENNE,%20Laetitia&WATTIAUX,%20Alain&SUBRAMANIAN,%20Mass%20A.&rft.genre=article


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record