HÖTING, Christoph; ECKERT, Helmut; MATAR, Samir F.; RODEWALD, Ute Ch.; PÖTTGEN, Rainer

doi:10.5560/ZNB.2014-3319

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HÖTING, Christoph
Institut für Anorganische und Analytische Chemie

ECKERT, Helmut
Institut für Physikalische Chemie

MATAR, Samir F.
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Zeitschrift fur Naturforschung B. 2014, vol. 69, n° 6, p. 305-312

Verlag der Zeitschrift Fuer Naturforschung

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The ThCr2Si2-type silicides YT2Si2 (T = Co, Ni, Cu, Ru, Rh, Pd) were synthesized from the elements by arc-melting. They were characterized by powder X-ray diffraction, and the structures were refined on the basis of single-crystal X-ray diffractometer data. The course of the lattice parameters shows a distinct anomaly for YRu2Si2 which has by far the smallest c/a ratio along with elongated Y-Si distances. Systematic 89Y solid-state NMR spectra show large Knight shifts arising from unpaired conduction electron spin density near the Fermi edge. The Knight shift decreases with increasing valence electron count (VEC), reflecting the sensitivity of this parameter to electronic properties. The particularly strong structural distortion observed in YRu2Si2 manifests itself in a sizeable magnetic shielding anisotropy. Electronic structure calculations for YRu2Si2 and YRh2Si2 reveal similar projected density of states (PDOS) shapes with an energy upshift of the Fermi level in YRh2Si2 due to the extra electron brought in by Rh. As a consequence, the PDOS at the Fermi energy is twice as large in the Ru compound as in the Rh compound. While both compounds show the major bonding interaction within the T2Si2 layers, YRh2Si2 exhibits significantly stronger Y-Si bonding.< Réduire

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The silicides YT2Si2 (T =Co, Ni, Cu, Ru, Rh, Pd): A systematic study by 89Y solid-state NMR spectroscopy

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