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Stereoselective ROP of rac- and meso-Lactides Using Achiral TBD as Catalyst
| dc.rights.license | open | en_US |
| hal.structure.identifier | Centre d'Innovation et de Recherche en Matériaux Polymères [CIRMAP] | |
| dc.contributor.author | MOINS, Sébastien | |
| hal.structure.identifier | Centre d'Innovation et de Recherche en Matériaux Polymères [CIRMAP] | |
| dc.contributor.author | HOYAS, Sébastien | |
| hal.structure.identifier | Université de Mons / University of Mons [UMONS] | |
| dc.contributor.author | LEMAUR, Vincent | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | ORHAN, Beste | |
| hal.structure.identifier | University of Birmingham [Birmingham] | |
| dc.contributor.author | DELLE CHIAIE, Kayla | |
| hal.structure.identifier | Université de Mons / University of Mons [UMONS] | |
| hal.structure.identifier | Service de Chimie des Matériaux Nouveaux | |
| hal.structure.identifier | Centre d'Innovation et de Recherche en Matériaux Polymères [CIRMAP] | |
| dc.contributor.author | LAZZARONI, Roberto | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | TATON, Daniel | |
| hal.structure.identifier | University of Birmingham [Birmingham] | |
| dc.contributor.author | DOVE, Andrew P. | |
| dc.contributor.author | COULEMBIER, Olivier | |
| dc.date.accessioned | 2021-07-06T07:29:46Z | |
| dc.date.available | 2021-07-06T07:29:46Z | |
| dc.date.issued | 2020-06-03 | |
| dc.identifier.issn | 2073-4344 | en_US |
| dc.identifier.uri | oai:crossref.org:10.3390/catal10060620 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/94980 | |
| dc.description.abstractEn | 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) polymerizes rac-lactide (rac-LA) to form highly isotactic polylactide (PLA) with a Pm = 0.88, while meso-LA yields heterotactic PLA (Pm ~ 0.8) at −75 °C. The stereocontrol of the cryogenic-based ring-opening polymerization comes from a perfect imbrication of both chiral LA and the propagating chiral end-group interacting with the achiral TBD catalyst. | |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution-NonCommercial-ShareAlike 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/us/ | * |
| dc.source | crossref | |
| dc.title.en | Stereoselective ROP of rac- and meso-Lactides Using Achiral TBD as Catalyst | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.3390/catal10060620 | en_US |
| dc.subject.hal | Chimie/Polymères | en_US |
| bordeaux.journal | Catalysts | en_US |
| bordeaux.page | 620 | en_US |
| bordeaux.volume | 10 | en_US |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | en_US |
| bordeaux.issue | 6 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| bordeaux.import.source | dissemin | |
| hal.identifier | hal-03278890 | |
| hal.version | 1 | |
| hal.date.transferred | 2021-07-06T07:29:51Z | |
| hal.export | true | |
| workflow.import.source | dissemin | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Catalysts&rft.date=2020-06-03&rft.volume=10&rft.issue=6&rft.spage=620&rft.epage=620&rft.eissn=2073-4344&rft.issn=2073-4344&rft.au=MOINS,%20S%C3%A9bastien&HOYAS,%20S%C3%A9bastien&LEMAUR,%20Vincent&ORHAN,%20Beste&DELLE%20CHIAIE,%20Kayla&rft.genre=article |