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Storage moduli and porosity of soft PDMS polyMIPEs can be controlled independently using thiol-ene click chemistry

hal.structure.identifierDepartment of Chemistry [Cincinnati]
dc.contributor.authorMCKENZIE, Tucker
hal.structure.identifierDepartment of Chemistry [Cincinnati]
dc.contributor.authorHEATON, Paul
hal.structure.identifierUniversity of Cincinnati [UC]
dc.contributor.authorRISHI, Kabir
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorKUMAR, Raj
hal.structure.identifierInstitut de Mécanique et d'Ingénierie [I2M]
dc.contributor.authorBRUNET, Thomas
hal.structure.identifierUniversity of Cincinnati [UC]
dc.contributor.authorBEAUCAGE, Gregory
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorMONDAIN-MONVAL, Olivier
IDREF: 084112654
hal.structure.identifierDepartment of Chemistry [Cincinnati]
dc.contributor.authorAYRES, Neil
dc.date.accessioned2021-05-14T09:32:32Z
dc.date.available2021-05-14T09:32:32Z
dc.date.created2020
dc.date.issued2020
dc.identifier.issn0024-9297
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/75972
dc.description.abstractEnPorous elastomeric polymers have been used in a wide range of applications because of their unique characteristics such as biocompatibility,gas permeability, thermal stability, and hydrophobic and dielectric properties. Poly(dimethyl siloxane) (PDMS), a commercially availableelastomer, has also been shown to exhibit specific acoustic properties. However, the material properties were limited because of a lack of control over the chemistry used to prepare the cross-linked PDMS elastomer. Here, the synthesis of PDMS-based polymerized medium internal-phase emulsions (polyMIPEs) with tunable storage shear moduli (G′) has been performed using macromolecular thiol−ene reactions. Storage shear modulus values from ∼38 to ∼330 kPa were achieved by changing the stoichiometric ratio of the thiol-to-ene-functionalized PDMS, whereas the porosity of the polyMIPEs was controlled by the volume of the aqueous phase used in the emulsion formulation. Very low sound velocities (∼40 m/s) through the porous materials were recorded using acoustic characterization. Therefore, this work provides an example of the synthesis of soft polyMIPEs with possible applications as acoustic materials.
dc.description.sponsorshipAdvanced Materials by Design - ANR-10-LABX-0042
dc.description.sponsorshipInitiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
dc.description.sponsorshipRevêtements fonctionnels acoustiques à base de Métamatériaux souples - ANR-15-CE08-0024
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enStorage moduli and porosity of soft PDMS polyMIPEs can be controlled independently using thiol-ene click chemistry
dc.typeArticle de revue
dc.identifier.doi10.1021/acs.macromol.0c00217
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecules
bordeaux.page3719-3727
bordeaux.volume53
bordeaux.hal.laboratoriesInstitut de Mécanique et d’Ingénierie de Bordeaux (I2M) - UMR 5295*
bordeaux.issue10
bordeaux.institutionUniversité de Bordeaux
bordeaux.institutionBordeaux INP
bordeaux.institutionCNRS
bordeaux.institutionINRAE
bordeaux.institutionArts et Métiers
bordeaux.peerReviewedoui
hal.identifierhal-02983309
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02983309v1
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