Application of living ionic polymerizations to the design of AB-type comb-like copolymers of various topologies and organizations
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | LANSON, David | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | ARIURA, Fumi | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | SCHAPPACHER, Michel | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | BORSALI, Redouane | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | DEFFIEUX, Alain | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 1598-5032 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20820 | |
| dc.description.abstractEn | Living anionic and cationic polymerizations have been combined to prepare various types of comb-like copolymers composed of polystyrene (PS) and polyisoprene (PI) blocks, with a precisely controlled architecture. According to the relative placement of these elementary building blocks, combs with randomly distributed PS and PI or with poly(styrene-b-isoprene) diblock branches (I & II, respectively) can be prepared. The reaction procedure initially includes the synthesis of a poly(chloroethylvinyl ether) using living cationic polymerization, which is used as the reactive backbone to successively graft PS-Li+ and PI-Li+ or PI-b-PS-Li+ to obtain structures (I) or (II). The synthesis of Janus-type PS-comb-b-PI-combs (III) initially involves the synthesis of a diblock backbone using living cationic polymerization, which bears two distinct reactive functions having either a protected or activated form. Living PS-Li+ and PI-Li+ are then grafted, in two separate steps, onto each of the reactive functions of the backbone, respectively. | |
| dc.language.iso | en | |
| dc.publisher | Springer | |
| dc.subject.en | polyisoprene | |
| dc.subject.en | polystyrene | |
| dc.subject.en | topology | |
| dc.subject.en | organization | |
| dc.subject.en | living anionic polymerization | |
| dc.subject.en | comb-like copolymers | |
| dc.title.en | Application of living ionic polymerizations to the design of AB-type comb-like copolymers of various topologies and organizations | |
| dc.type | Article de revue | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Research | |
| bordeaux.page | 173-177 | |
| bordeaux.volume | 15 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 2 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00279948 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00279948v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Research&rft.date=2007&rft.volume=15&rft.issue=2&rft.spage=173-177&rft.epage=173-177&rft.eissn=1598-5032&rft.issn=1598-5032&rft.au=LANSON,%20David&ARIURA,%20Fumi&SCHAPPACHER,%20Michel&BORSALI,%20Redouane&DEFFIEUX,%20Alain&rft.genre=article |
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