Poly(methyl methacrylate)-poly(caprolactone) AB and ABA block copolymers by combined ring-opening polymerization and atom transfer radical polymerization
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | SCHAPPACHER, Michèle | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | FUR, Nicolas | |
| dc.contributor.author | GUILLAUME, Sophie M. | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 0141-8130 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20804 | |
| dc.description.abstractEn | Chemical modification of alpha-hydroxy,omega-isopropylestertelechelic iPrO-PCL-OH, 1, and alpha,omega-dihydroxytelechelic HO-PCL-OH, 4, poly(epsilon-caprolactone) (PCL), synthesized from ring-opening polymerization using La((OPr)-Pr-i)(3) or Sm(BH4)(3)(THF)(3), allows the synthesis of the corresponding alpha-bromoester end-funetionalized polymers iPrO-PCL-.Br, 2, and Br-PCL-Br, 5, respectively. This direct procedure consists in an esterification of the hydroxy group(s) of 1 and 4 using 2-bromoisobutyryl bromide. These bromopolyesters 2 and 5 have subsequently been used as macroinitiators to synthesize, via atom transfer radical polymerization of methyl methacrylate (MMA), the new set of di- and triblock polyester-polyacrylate copolymers PCL-b-PMMA, 3, and PMMA-b-PCL-b-PMMA, 6, respectively. All (co)polymers are well defined as characterized by NMR and size exclusion chromatography analyses. In addition, the thermal properties of copolymers 3 and 6 have been investigated by differential scanning calorimetry. The self-assembly of triblock PMMA-b-PCL-b-PMMA, 6, copolymers into nanoparticles has been investigated by dynamic light scattering, atomic force microscopy, and optical microscopy techniques. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | self-assembly | |
| dc.subject.en | atom transfer radical polymerization | |
| dc.subject.en | di- and tri-block polyester-polyacrylate copolymers | |
| dc.subject.en | ring-opening polymerization | |
| dc.subject.en | bromopolyesters | |
| dc.subject.en | macroinitiators | |
| dc.title.en | Poly(methyl methacrylate)-poly(caprolactone) AB and ABA block copolymers by combined ring-opening polymerization and atom transfer radical polymerization | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ma070417q | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | International Journal of Biological Macromolecules | |
| bordeaux.page | 8887-8896 | |
| bordeaux.volume | 40 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 25 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00284176 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00284176v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=International%20Journal%20of%20Biological%20Macromolecules&rft.date=2007&rft.volume=40&rft.issue=25&rft.spage=8887-8896&rft.epage=8887-8896&rft.eissn=0141-8130&rft.issn=0141-8130&rft.au=SCHAPPACHER,%20Mich%C3%A8le&FUR,%20Nicolas&GUILLAUME,%20Sophie%20M.&rft.genre=article |
Fichier(s) constituant ce document
| Fichiers | Taille | Format | Vue |
|---|---|---|---|
|
Il n'y a pas de fichiers associés à ce document. |
|||