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Synthesis of Calibrated Poly(3,4-ethylenedioxythiophene) Latexes in Aqueous Dispersant Media

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorLECOMMANDOUX, Sebastien
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
dc.date.accessioned2020
dc.date.available2020
dc.date.created2008
dc.date.issued2008
dc.identifier.issn0743-7463
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20781
dc.description.abstractEnThe synthesis of spherical poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticles with a narrow size distribution was achieved in a dispersant aqueous medium. Various oxidants such as ammonium persulfate, iron(III) p-toluenesulfonate, and iron(111) trichloride were tested. A series of end-functionalized poly(ethylene oxide) (PEO) such as alpha-(3,4-ethylenedioxythiophene) PEO, alpha-(N-methyl pyrrole) PEO, alpha-(fluorene) PEO, alpha,omega-(N-methyl pyrrole) PEO, alpha,omega-(thiophene) PEO, and alpha,omega-(fluorene) PEO were compared as reactive stabilizers. The molar mass and the functionality of these reactive PEOs were found to be important parameters with respect to the control of particle size and size distribution. PEDOT samples were characterized by scanning electron microscopy (SEM), atomic force microscopy (AIM), size exclusion chromatography (SEC), and conductivity measurements.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enSynthesis of Calibrated Poly(3,4-ethylenedioxythiophene) Latexes in Aqueous Dispersant Media
dc.typeArticle de revue
dc.identifier.doi10.1021/la801591d
dc.subject.halChimie/Polymères
bordeaux.journalLangmuir
bordeaux.page11911-11920
bordeaux.volume24
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue20
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00340357
hal.version1
dc.subject.itcolloidal dispersions
dc.subject.itpolymer nanoparticles
dc.subject.itpedot nanoparticles
dc.subject.itstabilizers
dc.subject.itaqueous dispersion
dc.subject.itlatex
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00340357v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Langmuir&rft.date=2008&rft.volume=24&rft.issue=20&rft.spage=11911-11920&rft.epage=11911-11920&rft.eissn=0743-7463&rft.issn=0743-7463&rft.au=MUMTAZ,%20Muhammad&LECOMMANDOUX,%20Sebastien&CLOUTET,%20Eric&CRAMAIL,%20Henri&rft.genre=article


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