Synthesis of Calibrated Poly(3,4-ethylenedioxythiophene) Latexes in Aqueous Dispersant Media
LECOMMANDOUX, Sebastien
Laboratoire de Chimie des polymères organiques [LCPO]
Team 3 LCPO : Polymer Self-Assembly & Life Sciences
Laboratoire de Chimie des polymères organiques [LCPO]
Team 3 LCPO : Polymer Self-Assembly & Life Sciences
CLOUTET, Eric
Laboratoire de Chimie des polymères organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
See more >
Laboratoire de Chimie des polymères organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
LECOMMANDOUX, Sebastien
Laboratoire de Chimie des polymères organiques [LCPO]
Team 3 LCPO : Polymer Self-Assembly & Life Sciences
Laboratoire de Chimie des polymères organiques [LCPO]
Team 3 LCPO : Polymer Self-Assembly & Life Sciences
CLOUTET, Eric
Laboratoire de Chimie des polymères organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Laboratoire de Chimie des polymères organiques [LCPO]
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CRAMAIL, Henri
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Reduce
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Language
en
Article de revue
This item was published in
Langmuir. 2008, vol. 24, n° 20, p. 11911-11920
American Chemical Society
English Abstract
The synthesis of spherical poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticles with a narrow size distribution was achieved in a dispersant aqueous medium. Various oxidants such as ammonium persulfate, iron(III) ...Read more >
The synthesis of spherical poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticles with a narrow size distribution was achieved in a dispersant aqueous medium. Various oxidants such as ammonium persulfate, iron(III) p-toluenesulfonate, and iron(111) trichloride were tested. A series of end-functionalized poly(ethylene oxide) (PEO) such as alpha-(3,4-ethylenedioxythiophene) PEO, alpha-(N-methyl pyrrole) PEO, alpha-(fluorene) PEO, alpha,omega-(N-methyl pyrrole) PEO, alpha,omega-(thiophene) PEO, and alpha,omega-(fluorene) PEO were compared as reactive stabilizers. The molar mass and the functionality of these reactive PEOs were found to be important parameters with respect to the control of particle size and size distribution. PEDOT samples were characterized by scanning electron microscopy (SEM), atomic force microscopy (AIM), size exclusion chromatography (SEC), and conductivity measurements.Read less <
Italian Keywords
colloidal dispersions
polymer nanoparticles
pedot nanoparticles
stabilizers
aqueous dispersion
latex
Origin
Hal imported