Biomimetic processes II. Carbocationic polymerization of isopentenyl alcohol: A model for the synthesis of natural rubber?
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | FORESTIER, Thibault | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | PASETTO, Pamela | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | DEFFIEUX, Alain | |
hal.structure.identifier | Univ Akron, Dept Polymer Sci | |
dc.contributor.author | PUSKAS, Judit E. | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0928-4931 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20714 | |
dc.description.abstractEn | Natural rubber (poly(1.4-cis-isoprene), NR), a polymer of considerable industrial importance due to its exceptional properties, is exclusively produced from the cultivation of Hevea brasiliensis. After numerous attempts by polymer chemists to try to synthesize polyisoprene with very similar structures. none have been produced that exhibit such excellent properties. In this paper we analyze a new bio-inspired route towards NR based oil the carbocationic polymerization of isopentenyl pyrophosphate (IPP) (the natural monomer) and its derivatives. We report in ail initial study, the carbocationic polymerization of isopentenyl alcohol (IPOH) under various polymerization conditions. It is shown that oligomers are produced via 1,2 addition and not via the expected 1,4 addition. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | mechanistic study | |
dc.subject.en | natural rubber | |
dc.subject.en | cationic polymerization | |
dc.subject.en | isopentenyl alcohol | |
dc.title.en | Biomimetic processes II. Carbocationic polymerization of isopentenyl alcohol: A model for the synthesis of natural rubber? | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.msec.2008.06.025 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Materials Science and Engineering: C | |
bordeaux.page | 357-362 | |
bordeaux.volume | 29 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 2 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00380385 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00380385v1 | |
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