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Self-assembled nanostructures from peptide-synthetic hybrid block copolymers: Complex, stimuli-responsive rod-coil architectures
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | BABIN, Jerome | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | RODRIGUEZ-HERNANDEZ, Juan | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 3 LCPO : Polymer Self-Assembly & Life Sciences | |
| dc.contributor.author | LECOMMANDOUX, Sebastien | |
| dc.contributor.author | KLOK, H. A. | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | ACHARD, Marie-France | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.created | 2005 | |
| dc.date.issued | 2005 | |
| dc.identifier.issn | 1359-6640 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20707 | |
| dc.description.abstractEn | The synthesis, solution and solid state self-assembly properties of a series of polyisoprene-b-poly(epsilon-benzyloxycarbonyl-L-lysine) PI-b-PZLys and polyisoprene-b-poly(L-lysine) PI-b-PLys block copolymers have been examined. The formation of stimuli-responsive micelles in water has been studied as a function of pH and ionic strength using static and dynamic light scattering, UV-circular dichroism and transmission electron microscopy. The observed change in the micelles dimensions has been directly attributed to the conformational transition in the secondary structure of polypeptide chains. In bulk, these rod-coil copolymers form self-assembled structures that have been characterized using DSC, DMA, WAXS and SAXS techniques. Hexagonal in lamellar (HL) and more interestingly hexagonal in hexagonal (HH) morphologies have been evidenced as a function of the chemical composition. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | SCATTERING | |
| dc.subject.en | EQUILIBRIUM | |
| dc.subject.en | PHASE-BEHAVIOR | |
| dc.subject.en | L-LYSINE | |
| dc.subject.en | MORPHOLOGY | |
| dc.subject.en | MICROPHASE SEPARATION | |
| dc.subject.en | SUPRAMOLECULAR MATERIALS | |
| dc.subject.en | DIBLOCK COPOLYMERS | |
| dc.subject.en | POLYPEPTIDE BLOCK | |
| dc.subject.en | TRANSITION | |
| dc.title.en | Self-assembled nanostructures from peptide-synthetic hybrid block copolymers: Complex, stimuli-responsive rod-coil architectures | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/b403203a | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Faraday Discussions | |
| bordeaux.page | 179-192 | |
| bordeaux.volume | 128 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00392723 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00392723v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Faraday%20Discussions&rft.date=2005&rft.volume=128&rft.spage=179-192&rft.epage=179-192&rft.eissn=1359-6640&rft.issn=1359-6640&rft.au=BABIN,%20Jerome&RODRIGUEZ-HERNANDEZ,%20Juan&LECOMMANDOUX,%20Sebastien&KLOK,%20H.%20A.&ACHARD,%20Marie-France&rft.genre=article |
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