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hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorBIALEK, Marzena
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorDEFFIEUX, Alain
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorGUILLAUME, Sophie M.
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2005
dc.identifier.issn0014-3057
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20696
dc.description.abstractEnStyrene polymerization is investigated with neutral and cationic Ni(II) complexes, i.e. Ni(bipy)Me-2, 1, Ni(bipy)Br-2, 2, Ni(phen)Br-2, 3, or Ni(Me(2)phen)Br-2, 4, Ni(acac)(2), 5, (bipy = 2,2 '-bipyridine, phen = phenanthroline, Me,phen = 2,9-dimethyl-1, 10-phenanthroline, acac acetylacetonate), activated by [NHMe2Ph][B(C6F5)(4)] or B(C6F5)(3) as cocatalysts, in the presence of AlMe3. The influence on the polystyrene features and the reaction kinetics of the nickel complex and boron activator, the Al/Ni or B/Ni molar ratios as well as the monomer concentration are studied. Catalytic systems derived from 2, 3 or 5 and [NHMe2Ph][B(C6F5)(4)] at a Ni:B:Al ratio of 1: 1:5 are the most efficient at room temperature.
dc.language.isoen
dc.publisherElsevier
dc.subject.enpolyinerization
dc.subject.enstyrene
dc.subject.enboren
dc.subject.enkinetics
dc.subject.ennickel
dc.title.enStyrene polymerization using nickel(II) complexes as catalysts
dc.typeArticle de revue
dc.identifier.doi10.1016/j.eurpolymj.2005.05.024
dc.subject.halChimie/Polymères
bordeaux.journalEuropean Polymer Journal
bordeaux.page2678-2684
bordeaux.volume41
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue11
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00393806
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00393806v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Polymer%20Journal&rft.date=2005&rft.volume=41&rft.issue=11&rft.spage=2678-2684&rft.epage=2678-2684&rft.eissn=0014-3057&rft.issn=0014-3057&rft.au=BIALEK,%20Marzena&CRAMAIL,%20Henri&DEFFIEUX,%20Alain&GUILLAUME,%20Sophie%20M.&rft.genre=article


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