Styrene polymerization using nickel(II) complexes as catalysts
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | BIALEK, Marzena | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
dc.contributor.author | CRAMAIL, Henri | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | DEFFIEUX, Alain | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | GUILLAUME, Sophie M. | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2005 | |
dc.identifier.issn | 0014-3057 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20696 | |
dc.description.abstractEn | Styrene polymerization is investigated with neutral and cationic Ni(II) complexes, i.e. Ni(bipy)Me-2, 1, Ni(bipy)Br-2, 2, Ni(phen)Br-2, 3, or Ni(Me(2)phen)Br-2, 4, Ni(acac)(2), 5, (bipy = 2,2 '-bipyridine, phen = phenanthroline, Me,phen = 2,9-dimethyl-1, 10-phenanthroline, acac acetylacetonate), activated by [NHMe2Ph][B(C6F5)(4)] or B(C6F5)(3) as cocatalysts, in the presence of AlMe3. The influence on the polystyrene features and the reaction kinetics of the nickel complex and boron activator, the Al/Ni or B/Ni molar ratios as well as the monomer concentration are studied. Catalytic systems derived from 2, 3 or 5 and [NHMe2Ph][B(C6F5)(4)] at a Ni:B:Al ratio of 1: 1:5 are the most efficient at room temperature. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | polyinerization | |
dc.subject.en | styrene | |
dc.subject.en | boren | |
dc.subject.en | kinetics | |
dc.subject.en | nickel | |
dc.title.en | Styrene polymerization using nickel(II) complexes as catalysts | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.eurpolymj.2005.05.024 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | European Polymer Journal | |
bordeaux.page | 2678-2684 | |
bordeaux.volume | 41 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 11 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00393806 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00393806v1 | |
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