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Functionalized star-like polystyrenes as organic supports of a tridentate bis(imino)pyridinyliron/aluminic derivative catalytic system for ethylene polymerization

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorBOUILHAC, Cécile
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorDEFFIEUX, Alain
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2005
dc.identifier.issn1022-1336
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20693
dc.description.abstractEnStar-like polystyrenes composed of a microgel core with arms functionalized with a few hydroxy- or methoxy-ended ethylene oxide units were used as organic supports for a tridentate bis(imino)pyridinyliron catalyst towards ethylene polymerization. When used as supports of 2,6-bis[1-2,6(diisopropylphenyl)imino]ethylpyridynyl iron dichloride in the presence of various alkylaluminium compounds, the supported catalysts enabled the production, with a high catalytic activity, of polyethylene beads of a spherical morphology and high bulk density. A good control of the polyethylene molar mass distribution could also be achieved, which was explained by a lowering of the transfer reaction to the aluminium derivative, as compared to homogeneous conditions.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enSupport
dc.subject.enmicrogels
dc.subject.enpolyethylene
dc.subject.enstar polymers
dc.subject.encatalysts
dc.title.enFunctionalized star-like polystyrenes as organic supports of a tridentate bis(imino)pyridinyliron/aluminic derivative catalytic system for ethylene polymerization
dc.typeArticle de revue
dc.identifier.doi10.1002/marc.200500430
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Rapid Communications
bordeaux.page1619-1625
bordeaux.volume26
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue20
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00393816
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00393816v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2005&rft.volume=26&rft.issue=20&rft.spage=1619-1625&rft.epage=1619-1625&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=BOUILHAC,%20C%C3%A9cile&CLOUTET,%20Eric&CRAMAIL,%20Henri&DEFFIEUX,%20Alain&TATON,%20Daniel&rft.genre=article


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