Assembling the prenylneoflavone system through a Pechmann condensation/Mitsunobu reaction/Claisen rearrangement/olefin cross-metathesis sequence
| dc.rights.license | open | en_US |
| hal.structure.identifier | Neurocentre Magendie : Physiopathologie de la Plasticité Neuronale [U1215 Inserm - UB] | |
| dc.contributor.author | LOZINSKI, Oleg A. | |
| hal.structure.identifier | Institut des Sciences Moléculaires (Bordeaux) | |
| dc.contributor.author | BISTODEAU, J. | |
| hal.structure.identifier | Université de Bordeaux [UB] | |
| hal.structure.identifier | Acides Nucléiques : Régulations Naturelle et Artificielle [ARNA] | |
| dc.contributor.author | BENNETAU-PELISSERO, Catherine | |
| hal.structure.identifier | Taras Shevchenko National University of Kyiv | |
| dc.contributor.author | KHILYA, Vladimir P. | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | SHINKARUK, Svitlana | |
| dc.date.accessioned | 2025-03-20T15:06:37Z | |
| dc.date.available | 2025-03-20T15:06:37Z | |
| dc.date.issued | 2020 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/205586 | |
| dc.description.abstractEn | Abstract: The multistep synthesis of a prenylneoflavone through a sequence of the Mitsunobu reaction/Claisen rearrangement/olefin cross-metathesis reaction has been accomplished in 5% yield over six steps starting from commercially available 3-methoxyacetophenone. The sequence is shown to be compatible with a Pechmann condensation which proved to be a robust and cost-effective method for the assembling of the α-pyrone core. The results open doors to a general approach to the prenylneoflavone system starting from phenol and acetophenone derivatives. Graphic abstract: [Figure not available: see fulltext.] © 2020, Springer-Verlag GmbH Austria, part of Springer Nature. | |
| dc.language.iso | EN | en_US |
| dc.subject.en | Alkenes | |
| dc.subject.en | Flavonoids | |
| dc.subject.en | Heterocycles | |
| dc.subject.en | Metathesis | |
| dc.subject.en | Prenyl | |
| dc.title.en | Assembling the prenylneoflavone system through a Pechmann condensation/Mitsunobu reaction/Claisen rearrangement/olefin cross-metathesis sequence | |
| dc.title.alternative | Monatsh Chem | en_US |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1007/s00706-020-02584-8 | en_US |
| dc.subject.hal | Sciences du Vivant [q-bio]/Neurosciences [q-bio.NC] | en_US |
| dc.identifier.pubmed | 32346184 | en_US |
| bordeaux.journal | Monatshefte fur Chemie | en_US |
| bordeaux.page | 605-610 | en_US |
| bordeaux.volume | 151 | en_US |
| bordeaux.hal.laboratories | Neurocentre Magendie - U1215 | en_US |
| bordeaux.issue | 4 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | INSERM | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| hal.identifier | hal-04999121 | |
| hal.version | 1 | |
| hal.date.transferred | 2025-03-20T15:06:40Z | |
| hal.popular | non | en_US |
| hal.audience | Internationale | en_US |
| hal.export | true | |
| dc.rights.cc | Pas de Licence CC | en_US |
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