Solubility in CO(2) and carbonation studies of epoxidized fatty acid diesters: towards novel precursors for polyurethane synthesis
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | BOYER, Aurélie | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | TASSAING, Thierry | |
| hal.structure.identifier | Institut des Corps Gras | |
| dc.contributor.author | GADENNE, Benoît | |
| hal.structure.identifier | Institut des Corps Gras | |
| dc.contributor.author | ALFOS, Carine | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.created | 2010 | |
| dc.date.issued | 2010 | |
| dc.identifier.issn | 1463-9262 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20521 | |
| dc.description.abstractEn | Novel linear polyurethanes were synthesized by bulk polyaddition of diamines with two vegetable-based biscarbonates produced from oleic acid methyl ester. Internal carbonated fatty acid diester (ICFAD) and terminal carbonated fatty acid diester (TCFAD) were obtained by the reaction of their epoxide precursors with CO(2). Terminal epoxy fatty acid diester (TEFAD) was found to be more soluble and more reactive in CO(2) than internal epoxy fatty acid diester (IEFAD). Polyurethanes obtained by polyaddition of TCFAD and ICFAD with diamines exhibit molecular weights up to 13 500 g mol(-1) and glass transitions around -15 degrees C. Amide linkages were not observed when secondary diamine was used as the comonomer. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | SOYBEAN OIL | |
| dc.subject.en | VEGETABLE-OILS | |
| dc.subject.en | SOY-POLYOLS | |
| dc.subject.en | DIOXIDE | |
| dc.subject.en | POLYMERS | |
| dc.subject.en | ESTERS | |
| dc.subject.en | NETWORKS | |
| dc.subject.en | HYDROFORMYLATION | |
| dc.subject.en | EQUILIBRIA | |
| dc.subject.en | ROUTE | |
| dc.title.en | Solubility in CO(2) and carbonation studies of epoxidized fatty acid diesters: towards novel precursors for polyurethane synthesis | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c0gc00371a | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Green Chemistry | |
| bordeaux.page | 2205-2213 | |
| bordeaux.volume | 12 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 12 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00679371 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00679371v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Green%20Chemistry&rft.date=2010&rft.volume=12&rft.issue=12&rft.spage=2205-2213&rft.epage=2205-2213&rft.eissn=1463-9262&rft.issn=1463-9262&rft.au=BOYER,%20Aur%C3%A9lie&CLOUTET,%20Eric&TASSAING,%20Thierry&GADENNE,%20Beno%C3%AEt&ALFOS,%20Carine&rft.genre=article |
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