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dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorMOUGNIER, Sébastien Jun
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorFLEURY, Guillaume
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorCRAMAIL, Henri
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2012
dc.identifier.issn1022-1336
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20469
dc.description.abstractEnThe post-functionalization of poly(3-hexylthiophene) (P3HT) via various synthetic routes is reported. Well-defined and monofunctionalized ?-thiol-terminated P3HT, ?-carboxylic acid-terminated P3HT, ?-acrylate-terminated P3HT, and ?-methacrylate-terminated P3HT are obtained in high yields through a straightforward procedure. From those, different novel P3HT-based graft copolymers are synthesized following two routes: grafting onto and grafting through (macromonomer polymerization) methods. The synthesis of three types of graft copolymers is described. Each one has rod P3HT-grafted side chains on a coil main chain, which can be polyisoprene, poly(vinyl alcohol), or poly(butyl acrylate). Each copolymer is characterized by size-exclusion chromatography and NMR.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enpoly(3-hexylthiophene)
dc.subject.engraft copolymer
dc.subject.ensemiconducting copolymer
dc.subject.engrafting onto
dc.subject.engrafting through
dc.subject.enNMRP
dc.subject.enthiol-ene reaction
dc.title.enDesign of Well-Defined Monofunctionalized Poly(3-hexylthiophene)s: Toward the Synthesis of Semiconducting Graft Copolymers
dc.typeArticle de revue
dc.identifier.doi10.1002/marc.201100703
dc.subject.halChimie/Polymères
bordeaux.journalMacromolecular Rapid Communications
bordeaux.page703-709
bordeaux.volume33
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue8
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00758343
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00758343v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2012&rft.volume=33&rft.issue=8&rft.spage=703-709&rft.epage=703-709&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=MOUGNIER,%20S%C3%A9bastien%20Jun&BROCHON,%20Cyril&CLOUTET,%20Eric&FLEURY,%20Guillaume&CRAMAIL,%20Henri&rft.genre=article


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