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Design of Well-Defined Monofunctionalized Poly(3-hexylthiophene)s: Toward the Synthesis of Semiconducting Graft Copolymers
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
dc.contributor.author | MOUGNIER, Sébastien Jun | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | BROCHON, Cyril | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | FLEURY, Guillaume | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
dc.contributor.author | CRAMAIL, Henri | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
dc.contributor.author | HADZIIOANNOU, Georges | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1022-1336 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20469 | |
dc.description.abstractEn | The post-functionalization of poly(3-hexylthiophene) (P3HT) via various synthetic routes is reported. Well-defined and monofunctionalized ?-thiol-terminated P3HT, ?-carboxylic acid-terminated P3HT, ?-acrylate-terminated P3HT, and ?-methacrylate-terminated P3HT are obtained in high yields through a straightforward procedure. From those, different novel P3HT-based graft copolymers are synthesized following two routes: grafting onto and grafting through (macromonomer polymerization) methods. The synthesis of three types of graft copolymers is described. Each one has rod P3HT-grafted side chains on a coil main chain, which can be polyisoprene, poly(vinyl alcohol), or poly(butyl acrylate). Each copolymer is characterized by size-exclusion chromatography and NMR. | |
dc.language.iso | en | |
dc.publisher | Wiley-VCH Verlag | |
dc.subject.en | poly(3-hexylthiophene) | |
dc.subject.en | graft copolymer | |
dc.subject.en | semiconducting copolymer | |
dc.subject.en | grafting onto | |
dc.subject.en | grafting through | |
dc.subject.en | NMRP | |
dc.subject.en | thiol-ene reaction | |
dc.title.en | Design of Well-Defined Monofunctionalized Poly(3-hexylthiophene)s: Toward the Synthesis of Semiconducting Graft Copolymers | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/marc.201100703 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Macromolecular Rapid Communications | |
bordeaux.page | 703-709 | |
bordeaux.volume | 33 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.issue | 8 | |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00758343 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00758343v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2012&rft.volume=33&rft.issue=8&rft.spage=703-709&rft.epage=703-709&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=MOUGNIER,%20S%C3%A9bastien%20Jun&BROCHON,%20Cyril&CLOUTET,%20Eric&FLEURY,%20Guillaume&CRAMAIL,%20Henri&rft.genre=article |
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