Synthesis of isosorbide based polyurethanes: An isocyanate free method
dc.rights.license | open | |
hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
dc.contributor.author | BESSE, Vincent | |
hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
dc.contributor.author | AUVERGNE, Rémi | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | CARLOTTI, Stéphane | |
dc.contributor.author | BOUTEVIN, Gilles | |
hal.structure.identifier | Centre des Matériaux des Mines d'Alès [C2MA] | |
dc.contributor.author | OTAZAGHINE, Belkacem | |
hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
dc.contributor.author | CAILLOL, Sylvain | |
hal.structure.identifier | Ingénierie des Matériaux Polymères - Laboratoire des Matériaux Macromoléculaires [IMP-LMM] | |
dc.contributor.author | PASCAULT, Jean-Pierre | |
hal.structure.identifier | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM] | |
dc.contributor.author | BOUTEVIN, Bernard | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.created | 2012 | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1381-5148 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20458 | |
dc.description.abstractEn | The synthesis of isocyanate free polyurethanes is a major concern. This paper first reports the synthesis of new biobased isosorbide dicyclocarbonates from isosorbide. Then polyhydroxyurethanes (PHUs) were synthesized by a cyclocarbonate-amine step growth polyaddition with four commercial diamines (e.g. jeffamine D-400, 1,10 diaminodecane, diethylenetriamine and isophoronediamine). These unprecedented products, obtained with high yield, were characterized by 1H NMR, FTIR, DSC, SEC and TGA analyses. PHUs exhibited glass transition temperatures from 8 C to 59 C, and degradation temperatures (Td 5%) between 234 C and 255 C. Last but not least, the compounds produced during the degradation of these PHUs were analyzed by ATG-IR technique and showed that carbon dioxide and secondary amines are released. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | Carbonate | |
dc.subject.en | Thermal stability | |
dc.subject.en | Polyhydroxyurethane | |
dc.subject.en | Isosorbide | |
dc.subject.en | Renewable resources | |
dc.title.en | Synthesis of isosorbide based polyurethanes: An isocyanate free method | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.reactfunctpolym.2013.01.002 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Reactive and Functional Polymers | |
bordeaux.page | 588-594 | |
bordeaux.volume | 73 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00785178 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00785178v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Reactive%20and%20Functional%20Polymers&rft.date=2013&rft.volume=73&rft.spage=588-594&rft.epage=588-594&rft.eissn=1381-5148&rft.issn=1381-5148&rft.au=BESSE,%20Vincent&AUVERGNE,%20R%C3%A9mi&CARLOTTI,%20St%C3%A9phane&BOUTEVIN,%20Gilles&OTAZAGHINE,%20Belkacem&rft.genre=article |
Files in this item
Files | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |