Dendritic Carrier Based on PEG: Design and Degradation of Acid-sensitive Dendrimer-like Poly(ethylene oxide)s
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | FENG, Xiaoshuang | |
| hal.structure.identifier | Dept Surg, BethIsrael Deaconess Med Ctr [Harvard Univ, Sch Med] | |
| dc.contributor.author | CHAIKOF, Elliot L. | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | ABSALON, Christelle | |
| hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
| dc.contributor.author | DRUMMOND, Carlos | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | TATON, Daniel | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | GNANOU, Yves | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 1022-1336 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20432 | |
| dc.description.abstractEn | Degradable dendrimer-like PEO's were designed using an original ABC-type branching agent featuring a cleavable ketal group, following an iterative divergent approach based on the anionic ring opening polymerization (AROP) of ethylene oxide and arborization of PEO chain ends. A seventh generation dendrimer-like PEO carrying 192 peripheral hydroxyls and exhibiting a molar mass of 446 kg . mol(-1) was obtained in this way. The chemical degradation of these dendritic scaffolds was next successfully accomplished under acidic conditions, forming linear PEO chains of low molar mass (approximate to 2 kg . mol(-1)), as monitored by H-1 NMR, SEC, and MALDI-TOF mass spectrometry as well as by AFM. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.title.en | Dendritic Carrier Based on PEG: Design and Degradation of Acid-sensitive Dendrimer-like Poly(ethylene oxide)s | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/marc.201100459 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Rapid Communications | |
| bordeaux.page | 1722-1728 | |
| bordeaux.volume | 32 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 21 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00817490 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00817490v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2011&rft.volume=32&rft.issue=21&rft.spage=1722-1728&rft.epage=1722-1728&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=FENG,%20Xiaoshuang&CHAIKOF,%20Elliot%20L.&ABSALON,%20Christelle&DRUMMOND,%20Carlos&TATON,%20Daniel&rft.genre=article |
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