Synthesis of 1,4-polybutadiene-g-poly(ethylene oxide) via the macromonomer approach by ROMP
| dc.rights.license | open | |
| hal.structure.identifier | Institut des Molécules et Matériaux du Mans [IMMM] | |
| dc.contributor.author | LE, Dao | |
| hal.structure.identifier | Institut des Molécules et Matériaux du Mans [IMMM] | |
| dc.contributor.author | MONTEMBAULT, Véronique | |
| hal.structure.identifier | Institut des Molécules et Matériaux du Mans [IMMM] | |
| dc.contributor.author | PASCUAL, Sagrario | |
| hal.structure.identifier | Institut des Molécules et Matériaux du Mans [IMMM] | |
| dc.contributor.author | FONTAINE, Laurent | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | COLLETTE, Floraine | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | HÉROGUEZ, Valérie | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 1759-9954 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20423 | |
| dc.description.abstractEn | A poly(ethylene oxide) (PEO) macromonomer end-capped by a polymerizable cyclobutene group has been polymerized by ring-opening metathesis polymerization (ROMP) using Grubbs' second generation (G2) and third generation (G3) catalysts. The macromonomer having a hydrophilic PEO conjugated with a hydrophobic cyclobutene moiety shows self-association properties in water as demonstrated by fluorescence spectroscopy. Therefore, the PEO-based cyclobutene macromonomer was subjected to ROMP both in miniemulsion and in solution. Well-defined 1,4-polybutadiene-g-PEOs with molecular weights ranging from 19 800 to 38 000 g mol(-1) were obtained using G2 in solution with excellent control over molecular weight distribution (PDI = 1.07-1.11). | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry - RSC | |
| dc.subject.en | CATALYSTS | |
| dc.subject.en | POLYMERS | |
| dc.subject.en | AQUEOUS-MEDIUM | |
| dc.subject.en | MINIEMULSION | |
| dc.subject.en | RING-OPENING-METATHESIS | |
| dc.subject.en | CYLINDRICAL MOLECULAR BRUSHES | |
| dc.subject.en | RADICAL POLYMERIZATION | |
| dc.subject.en | GRAFT-COPOLYMERS | |
| dc.subject.en | RAFT POLYMERIZATION | |
| dc.subject.en | BLOCK-COPOLYMERS | |
| dc.title.en | Synthesis of 1,4-polybutadiene-g-poly(ethylene oxide) via the macromonomer approach by ROMP | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c3py21103g | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Polymer Chemistry | |
| bordeaux.page | 2168-2173 | |
| bordeaux.volume | 4 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 6 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00818348 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00818348v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2013&rft.volume=4&rft.issue=6&rft.spage=2168-2173&rft.epage=2168-2173&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=LE,%20Dao&MONTEMBAULT,%20V%C3%A9ronique&PASCUAL,%20Sagrario&FONTAINE,%20Laurent&COLLETTE,%20Floraine&rft.genre=article |
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