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dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorFÈVRE, Maréva
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorVIGNOLLE, Joan
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2013
dc.identifier.issn1759-9954
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20393
dc.description.abstractEnVarious imidazolium-2-carboxylates and (benz) imidazolium hydrogen carbonates, denoted as NHC-CO2 adducts and [NHC(H)][HCO3], respectively, were employed as masked N-heterocyclic carbenes (NHCs) to bring about both the ring opening polymerisation (ROP) of D, L-lactide (LA) and the group transfer polymerisation (GTP) of methyl methacrylate (MMA). Polymerisation reactions could be performed at room temperature by generation of related free NHCs by a simple solvation effect. Catalytic efficiencies of imidazolium-2-carboxylates were found to be approximately three times higher than that of their hydrogen carbonate counterparts for the ROP of D, L-LA, except in the particular case of 1,3-dicyclohexylbenzimidazolium hydrogen carbonate that exhibited a similar catalytic performance to that of NHC-CO2 adducts. The catalytic efficiencies of free NHCs and NHC precursors were thus in the following order: [NHC(H)][HCO3] < NHC-CO2 adducts << free NHCs. Only NHC-CO2 adducts allowed the catalysis of the GTP of MMA in bulk in a controlled manner, [NHC(H)][HCO3] precursor salts being poorly soluble in the monomer substrate, causing a loss of control of GTP under solvent-less conditions.
dc.language.isoen
dc.publisherRoyal Society of Chemistry - RSC
dc.subject.enLATENT CATALYSTS
dc.subject.enPOLY(ETHYLENE OXIDE)S
dc.subject.enMEDIATED ZWITTERIONIC POLYMERIZATION
dc.subject.enIMIDAZOLIUM CARBOXYLATES
dc.subject.enLIVING POLYMERIZATION
dc.subject.enBLOCK-COPOLYMERS
dc.subject.enIONIC LIQUIDS
dc.subject.en(METH)ACRYLIC MONOMERS
dc.subject.enPOLYURETHANE SYNTHESIS
dc.subject.enETHYLENE-OXIDE
dc.title.enAzolium hydrogen carbonates and azolium carboxylates as organic pre-catalysts for N-heterocyclic carbene-catalysed group transfer and ring-opening polymerisations
dc.typeArticle de revue
dc.identifier.doi10.1039/c2py20915b
dc.subject.halChimie/Polymères
bordeaux.journalPolymer Chemistry
bordeaux.page1995-2003
bordeaux.volume4
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue6
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00930998
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00930998v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Polymer%20Chemistry&amp;rft.date=2013&amp;rft.volume=4&amp;rft.issue=6&amp;rft.spage=1995-2003&amp;rft.epage=1995-2003&amp;rft.eissn=1759-9954&amp;rft.issn=1759-9954&amp;rft.au=F%C3%88VRE,%20Mar%C3%A9va&amp;VIGNOLLE,%20Joan&amp;TATON,%20Daniel&amp;rft.genre=article


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