Investigations into Competitive Cycloaddition/Cyclization or Elimination from 1,1-Dimethyl-propargylcarbamates of Anilines
| dc.rights.license | open | |
| hal.structure.identifier | Synthèse et réactivité des substances naturelles [SRSN] | |
| dc.contributor.author | DELATOUCHE, Régis | |
| hal.structure.identifier | Synthèse et réactivité des substances naturelles [SRSN] | |
| dc.contributor.author | LESAGE, Aurélien | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | COLLETTE, Floraine | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | HÉROGUEZ, Valérie | |
| hal.structure.identifier | Synthèse et réactivité des substances naturelles [SRSN] | |
| dc.contributor.author | BERTRAND, Philippe | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 0004-9425 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20364 | |
| dc.description.abstractEn | The copper-catalyzed reaction of 1,1-dimethyl-O-propargyl aniline carbamates was studied and revealed the unexpected formation of oxazolidin-2-ones and alkylamines. An in-depth study of the reaction conditions showed that the formation of these products was highly dependent on the solvent, copper catalyst and aniline substituents. The reaction can be oriented towards oxazolidinones in pyridine and alkylamines in ethanol, whereas cycloaddition can be achieved in dry tetrahydrofuran. | |
| dc.language.iso | en | |
| dc.publisher | CSIRO Publishing | |
| dc.subject.en | ISOCYANATES | |
| dc.subject.en | 4-METHYLENE-2-OXAZOLIDINONES | |
| dc.subject.en | ALCOHOLS | |
| dc.subject.en | CLICK CHEMISTRY | |
| dc.subject.en | CATALYZED CYCLIZATION | |
| dc.subject.en | PROPARGYL CARBONATES | |
| dc.subject.en | CONVENIENT SYNTHESIS | |
| dc.subject.en | MILD CONDITIONS | |
| dc.subject.en | AMINES | |
| dc.subject.en | BOND | |
| dc.title.en | Investigations into Competitive Cycloaddition/Cyclization or Elimination from 1,1-Dimethyl-propargylcarbamates of Anilines | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1071/CH10344 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Australian Journal of Chemistry | |
| bordeaux.page | 166-173 | |
| bordeaux.volume | 64 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 2 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00947153 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00947153v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Australian%20Journal%20of%20Chemistry&rft.date=2011&rft.volume=64&rft.issue=2&rft.spage=166-173&rft.epage=166-173&rft.eissn=0004-9425&rft.issn=0004-9425&rft.au=DELATOUCHE,%20R%C3%A9gis&LESAGE,%20Aur%C3%A9lien&COLLETTE,%20Floraine&H%C3%89ROGUEZ,%20Val%C3%A9rie&BERTRAND,%20Philippe&rft.genre=article |
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