Ring Opening Polymerization of DL-Lactide Using A Supramolecular Sulfonamide - Tertiary Amine Organocatalytic System
| dc.rights.license | open | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | THOMAS, Coralie | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | BIBAL, Brigitte | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2012 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20356 | |
| dc.description.abstractEn | Sulfonamides are common ligands for organometallic catalysis in the Ring Opening Polymerization (ROP) of cyclic esters. In our quest for original Hydrogen-bonding catalytic systems, our goal was to use a sulfonamide derivative as an electrophilic activator of DL-lactide in partnership with a tertiary amine, as a nucleophilic activator of the initiator and growing polymer chain. Several sulfonamides were synthesized and tested in the ROP of DL-lactide. The impact of sulfonamide substituents was analyzed to better understand the H-bonds involved in the process. | |
| dc.language.iso | en | |
| dc.subject.en | Hydrogen bond | |
| dc.subject.en | lfonamides | |
| dc.subject.en | Sparteine | |
| dc.subject.en | Ring Opening Polymerization | |
| dc.subject.en | Lactide | |
| dc.subject.en | Organocatalysis | |
| dc.title.en | Ring Opening Polymerization of DL-Lactide Using A Supramolecular Sulfonamide - Tertiary Amine Organocatalytic System | |
| dc.type | Article de revue | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | All Results Journal Chem | |
| bordeaux.page | 7-11 | |
| bordeaux.volume | 3 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00950648 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00950648v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=All%20Results%20Journal%20Chem&rft.date=2012&rft.volume=3&rft.spage=7-11&rft.epage=7-11&rft.au=THOMAS,%20Coralie&PERUCH,%20Fr%C3%A9d%C3%A9ric&BIBAL,%20Brigitte&rft.genre=article |
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