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dc.rights.licenseopen
hal.structure.identifierRhodia Recherches
dc.contributor.authorDESTARAC, M.
hal.structure.identifierRhodia Recherches
dc.contributor.authorBZDUCHA, W.
hal.structure.identifierRhodia Recherches
hal.structure.identifierLaboratoire de Chimie des polymères organiques [LCPO]
dc.contributor.authorTATON, Daniel
hal.structure.identifierLaboratoire de synthèse organique [DCSO]
dc.contributor.authorGAUTHIER-GILLAIZEAU, Isabelle
hal.structure.identifierLaboratoire de synthèse organique [DCSO]
dc.contributor.authorZARD, Samir
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2002
dc.identifier.issn1022-1336
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20345
dc.description.abstractEnThe capability of three chain-transfer agents, O-alkyl-S-(1-ethoxycarbonyl)ethyl xanthates (CH3-CHCO2C2H5)S(C=S)OZ', to control the free-radical polymerization of styrene and ethyl acrylate by the MADIX process was examined. The reactivity of the xanthates varied according to the following trend: Z' = CH2CH3 < CH2CF3 < CH[P(O)(OEt)2]CF3. This change in reactivity allowed a lowering of the polydispersity index from 2.0 for Z' = CH2CH3 to 1.15 for Z' = CH[P(O)(OEt)2]CF3 in the case of the polymerization of styrene.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enXanthates as chain-transfer agents in controlled radical polymerization (MADIX): Structural effect of the O-alkyl group
dc.typeArticle de revue
dc.identifier.doi10.1002/marc.200290002
bordeaux.journalMacromolecular Rapid Communications
bordeaux.page1049-1054
bordeaux.volume23
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue17
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00954865
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00954865v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Macromolecular%20Rapid%20Communications&amp;rft.date=2002&amp;rft.volume=23&amp;rft.issue=17&amp;rft.spage=1049-1054&amp;rft.epage=1049-1054&amp;rft.eissn=1022-1336&amp;rft.issn=1022-1336&amp;rft.au=DESTARAC,%20M.&amp;BZDUCHA,%20W.&amp;TATON,%20Daniel&amp;GAUTHIER-GILLAIZEAU,%20Isabelle&amp;ZARD,%20Samir&amp;rft.genre=article


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