Pluronic and beta-cyclodextrin in water: from swollen micelles to self-assembled crystalline platelets
| dc.rights.license | open | |
| hal.structure.identifier | Ecole nationale supérieure de chimie, polymères et materiaux de strasbourg (ECPM) | |
| dc.contributor.author | PERRY, Christophe | |
| hal.structure.identifier | Institut de Physique et Chimie des Matériaux de Strasbourg [IPCMS] | |
| dc.contributor.author | HEBRAUD, Pascal | |
| hal.structure.identifier | Institut d'électronique du solide et des systèmes (Strasbourg) | |
| dc.contributor.author | GERNIGON, Véronique | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | BROCHON, Cyril | |
| hal.structure.identifier | Laboratoire Léon Brillouin [LLB - UMR 12] | |
| dc.contributor.author | LAPP, Alain | |
| hal.structure.identifier | Institut Laue-Langevin [ILL] | |
| dc.contributor.author | LINDNER, Peter | |
| hal.structure.identifier | Ecole nationale supérieure de chimie, polymères et materiaux de strasbourg (ECPM) | |
| dc.contributor.author | SCHLATTER, Guy | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 1744-683X | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20338 | |
| dc.description.abstractEn | Cyclodextrin (CD) and copolymers of polyethylene oxide (PEO)-b-polypropylene oxide (PPO)-b-polyethylene oxide (PEO) (pluronics) form inclusion complexes (ICs) in water. A solution of native unmodified beta-CD was mixed with a dilute solution of pluronic F-68 at 70 degrees C. The temperature was then quickly cooled down below the critical micellization temperature (CMT) of the triblock-copolymer. The mixture was left ageing at controlled temperature until turbidity, opalescence and finally sedimentation occurred. The self-organization behaviour of the system was investigated by small angle neutron scattering (SANS) in D(2)O. At high temperature the formation of stable, beta-CD-swollen micelles was observed. ICs were formed while the mixture was thermally quenched. Their subsequent aggregation was studied by SANS, and the resulting structures were observed by atomic force microscopy (AFM) after film deposition. With time, we evidenced the formation of thin platelets (17 nm) having large planar dimensions (about 1 mu m at 20 degrees C to 4 mu m at 40 degrees C) and a crystallographic angle of 105.4 degrees. Fitting the SANS data, a model was proposed where the growth of a platelet occurred through association of IC bundles in a characteristic time of 190 min. Each bundle (2.4 nm in radius and 17 nm in length) of well-organized IC molecules is formed in a characteristic time of 17 min at 20 degrees C. The platelets are original because of their crystalline nature with well-defined angles, and their very flat and rigid shape. Moreover they form effortlessly through self-assembling in water. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | THERMORESPONSIVE POLYROTAXANES | |
| dc.subject.en | BLOCK-COPOLYMER | |
| dc.subject.en | POLY(PROPYLENE GLYCOL) | |
| dc.subject.en | MULTIBLOCK COPOLYMER BEHAVIOR | |
| dc.subject.en | GLYCOL) TRIBLOCK COPOLYMER | |
| dc.subject.en | CD/PEO-BASED POLYROTAXANES | |
| dc.subject.en | INCLUSION COMPLEXES | |
| dc.subject.en | ALPHA-CYCLODEXTRIN | |
| dc.subject.en | AQUEOUS-SOLUTION | |
| dc.subject.en | POLY(ETHYLENE GLYCOL) | |
| dc.title.en | Pluronic and beta-cyclodextrin in water: from swollen micelles to self-assembled crystalline platelets | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c0sm01092h | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Soft Matter | |
| bordeaux.page | 3502-3512 | |
| bordeaux.volume | 7 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 7 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00956829 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00956829v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Soft%20Matter&rft.date=2011&rft.volume=7&rft.issue=7&rft.spage=3502-3512&rft.epage=3502-3512&rft.eissn=1744-683X&rft.issn=1744-683X&rft.au=PERRY,%20Christophe&HEBRAUD,%20Pascal&GERNIGON,%20V%C3%A9ronique&BROCHON,%20Cyril&LAPP,%20Alain&rft.genre=article |
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