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A well-defined polyelectrolyte and its copolymers by reversible addition fragmentation chain transfer (RAFT) polymerization: synthesis and applications

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorAISSOU, Karim
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorKATSIGIANNOPOULOS, Dimitrios
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2015
dc.identifier.issn2046-2069
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20216
dc.description.abstractEnReversible Addition-Fragmentation Chain Transfer (RAFT) polymerization of 4-styrenesulfonyl(trifluoromethyl-sulfonyl)imide potassium salt (SKTFSI) in N,N-dimethylformamide (DMF) solution was carried out using 2-(dodecylsulfanylthiocarbonylsulfanyl)-2-methylpropionic acid (DDMAT) as a reversible chain transfer agent in the presence of 2,2'-azobisisobutyronitrile (AIBN) at 65 degrees C in an inert atmosphere. We showed both homopolymers and well-defined polyelectrolyte diblock copolymer systems could be prepared through the direct polymerization of the charged SKTFSI monomer. To produce Li-ion polyelectrolytes, a cation exchange methodology (e.g. K+ -> Li+) was used. Self-assembly of single-ion diblock copolymer thin films consisting of a Li-ion conductive PSLiTFSI block associated with a glassy polystyrene block is also demonstrated.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enCONDUCTIVITY
dc.subject.enWATER
dc.subject.enLITHIUM BATTERIES
dc.subject.enTHERMAL-DEGRADATION
dc.subject.enTRIBLOCK COPOLYMERS
dc.subject.enELECTROLYTES
dc.title.enA well-defined polyelectrolyte and its copolymers by reversible addition fragmentation chain transfer (RAFT) polymerization: synthesis and applications
dc.typeArticle de revue
dc.identifier.doi10.1039/c5ra19730a
dc.subject.halChimie/Polymères
bordeaux.journalRSC Advances
bordeaux.page98559-98565
bordeaux.volume5
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue119
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01369646
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01369646v1
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