Triflate esters as in-situ generated initiating system for carbocationic polymerization of vinyl ethers, isoprene, myrcene and ocimene
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | RADCHENKO, Alexei V. | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | BOUCHEKIF, Hassen | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2017 | |
| dc.identifier.issn | 0014-3057 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20134 | |
| dc.description.abstractEn | Thermo-induced carbocationic polymerization of isobutyl vinyl ether (IBVE), isoprene, myrcene and ocimene is reported using triflate esters as in-situ generated single-molecule initiating system. 3-Methyl-2-butenyl triflate is used for IBVE polymerization at room temperature resulting in polymers with Mn ∼ 9500 g mol−1 and Mw/Mn ∼ 2. Triflate-ester initiated polymerization of isoprene leads to oligomers with branched and ultimately cross-linked structures. Myrcene cationic polymerization, in CH2Cl2 or cyclohexane, using 2-propenyl triflate and 1-(4-metoxyphenyl)ethyl triflate as initiators yields low molar mass oligomyrcenes with loss of olefinic protons. Ocimene cationic polymerization is reported for the first time. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Polymerization | |
| dc.subject.en | Crosslinked structures | |
| dc.subject.en | Olefinic protons | |
| dc.subject.en | Cationic polymerization | |
| dc.subject.en | Isobutylvinyl ether | |
| dc.subject.en | Isoprene | |
| dc.subject.en | Myrcene | |
| dc.subject.en | Ocimene | |
| dc.subject.en | Triflate ester | |
| dc.subject.en | Esters | |
| dc.subject.en | Ethers | |
| dc.subject.en | In situ processing | |
| dc.subject.en | Monoterpenes | |
| dc.subject.en | Organic compounds | |
| dc.subject.en | Single molecule | |
| dc.subject.en | Triflates | |
| dc.subject.en | Vinyl ethers | |
| dc.subject.en | Carbocationic polymerization | |
| dc.title.en | Triflate esters as in-situ generated initiating system for carbocationic polymerization of vinyl ethers, isoprene, myrcene and ocimene | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.eurpolymj.2017.02.001 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | European Polymer Journal | |
| bordeaux.page | 34-41 | |
| bordeaux.volume | 89 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01473872 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01473872v1 | |
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