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Partially Biosourced Poly(1,2,3-triazolium)-Based Diblock Copolymers Derived from Levulinic Acid

dc.rights.licenseopen
dc.contributor.authorKALLEL ELLOUMI, Amira
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorABDELHEDI MILADI, Imen
hal.structure.identifierIngénierie des Matériaux Polymères [IMP]
dc.contributor.authorSERGHEI, Anatoli
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierInstitut Européen des membranes [IEM]
dc.contributor.authorAISSOU, Karim
hal.structure.identifierLaboratoire de Chimie Organique Structurale et Macromoléculaire [LR99ES14]
dc.contributor.authorBEN ROMDHANE, Hatem
hal.structure.identifierIngénierie des Matériaux Polymères - Laboratoire des Matériaux Polymères et des Biomatériaux [IMP-LMPB]
dc.contributor.authorDROCKENMULLER, Eric
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2018
dc.identifier.issn0024-9297
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/20016
dc.description.abstractEnPartially biobased poly(1,2,3-triazolium)s are synthesized by reversible additionfragmentation chain transfer (RAFT) polymerization of tailor-made 1,2,3-triazole-functionalized (meth)acrylate monomers derived from levulinic acid, followed by N-alkylation of the 1,2,3-triazole moieties by methyl iodide (CH3I) and subsequent anion exchange with lithium bis(trifluoromethylsulfonyl)imide (LiTFSI). Chain extension of a 1,2,3-triazole-functionalized polymethacrylate by RAFT polymerization of styrene followed by N-alkylation with CH3I and anion exchange with LiTFSI affords two poly(1,2,3-triazole)- and two poly(1,2,3-triazolium)-based diblock copolymers (BCPs) with different weight fractions of each block. Discussion of the structure/properties relationships of all obtained materials is based on NMR spectroscopy, size exclusion chromatography, differential scanning calorimetry, thermogravimetric analysis, and broadband dielectric spectroscopy. The morphological and self-assembling properties of neutral and charged BCPs in bulk and in thin films are investigated by small-angle X-ray scattering and atomic force microscopy experiments, respectively.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enSENSITIZED SOLAR-CELLS
dc.subject.enANION-EXCHANGE MEMBRANES
dc.subject.enTRANSFER RAFT POLYMERIZATION
dc.subject.enMEDIATED RADICAL POLYMERIZATION
dc.subject.enPOLYMERIZED IONIC LIQUID
dc.subject.enSOLID ELECTROLYTES
dc.subject.enVINYL LEVULINATE
dc.subject.enBLOCK-COPOLYMERS
dc.subject.enPOLY(IONIC LIQUID)S
dc.subject.enTRIBLOCK COPOLYMERS
dc.title.enPartially Biosourced Poly(1,2,3-triazolium)-Based Diblock Copolymers Derived from Levulinic Acid
dc.typeArticle de revue
dc.identifier.doi10.1021/acs.macromol.8b00962
dc.subject.halChimie
dc.subject.halChimie/Polymères
dc.subject.halChimie/Matériaux
bordeaux.journalMacromolecules
bordeaux.page5820 - 5830
bordeaux.volume51
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue15
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-01872202
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01872202v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecules&rft.date=2018&rft.volume=51&rft.issue=15&rft.spage=5820%20-%205830&rft.epage=5820%20-%205830&rft.eissn=0024-9297&rft.issn=0024-9297&rft.au=KALLEL%20ELLOUMI,%20Amira&ABDELHEDI%20MILADI,%20Imen&SERGHEI,%20Anatoli&TATON,%20Daniel&AISSOU,%20Karim&rft.genre=article


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