Homochiral versus Heterochiral Dimeric Helical Foldamer Bundles: Chlorinated‐Solvent‐Dependent Self‐Sorting
| dc.rights.license | open | en_US |
| dc.contributor.author | MENKE, Friedericke | |
| dc.contributor.author | WICHER, Barbara | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | MAURIZOT, Victor | |
| dc.contributor.author | HUC, Ivan | |
| dc.date.accessioned | 2024-05-02T08:15:20Z | |
| dc.date.available | 2024-05-02T08:15:20Z | |
| dc.date.issued | 2023 | |
| dc.identifier.issn | 1433-7851 | en_US |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/199565 | |
| dc.description.abstractEn | Aromatic oligoamide sequences programmed to fold into stable helical conformations were designed to display a linear array of hydrogen‐bond donors and acceptors at their surface. Sequences were prepared by solid‐phase synthesis. Solution 1 H NMR spectroscopic studies and solid‐state crystallographic structures demonstrated the formation of stable hydrogen‐bond‐mediated dimeric helix bundles that could be either heterochiral (with a P and an M helix) or homochiral (with two P or two M helices). Formation of the hetero‐ or homochiral dimers could be driven quantitatively using different chlorinated solvents—exemplifying a remarkable case of either social or narcissistic chiral self‐sorting or upon imposing absolute handedness to the helices to forbid PM species. | |
| dc.language.iso | EN | en_US |
| dc.title.en | Homochiral versus Heterochiral Dimeric Helical Foldamer Bundles: Chlorinated‐Solvent‐Dependent Self‐Sorting | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1002/anie.202217325 | en_US |
| dc.subject.hal | Chimie/Chimie organique | en_US |
| bordeaux.journal | Angewandte Chemie International Edition | en_US |
| bordeaux.page | e202217325 | en_US |
| bordeaux.volume | 62 | en_US |
| bordeaux.hal.laboratories | CBMN : Chimie & de Biologie des Membranes & des Nano-objets - UMR 5248 | en_US |
| bordeaux.issue | 12 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| bordeaux.import.source | hal | |
| hal.identifier | hal-04274850 | |
| hal.version | 1 | |
| hal.popular | non | en_US |
| hal.audience | Internationale | en_US |
| hal.export | false | |
| workflow.import.source | hal | |
| dc.rights.cc | Pas de Licence CC | en_US |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2023&rft.volume=62&rft.issue=12&rft.spage=e202217325&rft.epage=e202217325&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=MENKE,%20Friedericke&WICHER,%20Barbara&MAURIZOT,%20Victor&HUC,%20Ivan&rft.genre=article |
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