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Combining local conformational preferences and solvophobic effects in helical aromatic oligoamide foldamers

dc.rights.licenseopenen_US
dc.contributor.authorTENG, Binhao
dc.contributor.authorATCHER, Joan
dc.contributor.authorALLMENDINGER, Lars
dc.contributor.authorDOUAT, Celine
hal.structure.identifierChimie et Biologie des Membranes et des Nanoobjets [CBMN]
dc.contributor.authorFERRAND, Yann
dc.contributor.authorHUC, Ivan
dc.date.accessioned2024-04-23T10:18:27Z
dc.date.available2024-04-23T10:18:27Z
dc.date.issued2023-05-03
dc.identifier.issn1477-0520en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/199277
dc.description.abstractEnRemoving features that locally control conformations in aromatic oligoamides hampers helical folding in DMSO but not in water where the loss is compensated by hydrophobic effects. Aromatic oligoamide foldamers were designed using a newly-developed monomer so that helical folding was promoted by both local conformation preferences and solvophobic effects. Solid phase synthesis provided quick access to the desired sequences.Sharp solvent-driven conformational transitions that depended on sequence length were evidenced by both NMR and UV absorption spectroscopies
dc.language.isoENen_US
dc.title.enCombining local conformational preferences and solvophobic effects in helical aromatic oligoamide foldamers
dc.typeArticle de revueen_US
dc.identifier.doi10.1039/D3OB00473Ben_US
dc.subject.halChimieen_US
bordeaux.journalOrganic & Biomolecular Chemistryen_US
bordeaux.page3525-3530en_US
bordeaux.volume21en_US
bordeaux.hal.laboratoriesCBMN : Chimie & de Biologie des Membranes & des Nano-objets - UMR 5248en_US
bordeaux.issue17en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionCNRSen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcehal
hal.identifierhal-04234434
hal.version1
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
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