Synthesis of Fatty Acid-Based Polyesters and Their Blends with Poly(L-lactide) as a Way To Tailor PLLA Toughness
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | LEBARBÉ, Thomas | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | GRAU, Etienne
IDREF: 187909261 | |
| hal.structure.identifier | Institut des Corps Gras [ITERG] | |
| dc.contributor.author | GADENNE, Benoît | |
| hal.structure.identifier | Institut des Corps Gras [ITERG] | |
| dc.contributor.author | ALFOS, Carine | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 2168-0485 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19778 | |
| dc.description.abstractEn | Polylactide (PLA) is one of the most mature biobased and biocompostable plastics currently in the market. Despite its mechanical properties comparable to the ones of some mainstream petroleum-based thermoplastics (PS, for instance), PLA inherent brittleness and heat sensitivity are issues for its full industrial development. In this study, we investigated the melt-blending of PLLA (poly-L-lactide) with fatty acid-based flexible polyesters as an efficient way to tailor PLLA toughness. To that aim, a set of aliphatic polyesters has been developed by taking benefit of the large range of biobased building blocks that can be obtained from plant oils. Melt-blending of the so-formed polyesters with PLLA resulted in improved properties that can be finely tailored by varying the structure and the properties of the plant-based polyester additives. | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | impact resistance | |
| dc.subject.en | crystallization | |
| dc.subject.en | toughening | |
| dc.subject.en | plant oils | |
| dc.subject.en | TOUGHENING MODIFICATION | |
| dc.subject.en | GLYCIDYL METHACRYLATE | |
| dc.subject.en | Sustainable polymers | |
| dc.subject.en | Poly(L-lactide) | |
| dc.subject.en | BIODEGRADABLE IMPACT MODIFIERS | |
| dc.subject.en | REACTIVE PROCESSING AGENT | |
| dc.subject.en | POLY(LACTIC ACID) | |
| dc.subject.en | MECHANICAL-PROPERTIES | |
| dc.subject.en | POLYMER SCIENCE | |
| dc.subject.en | PHASE-STRUCTURE | |
| dc.subject.en | LACTIC-ACID | |
| dc.subject.en | polyesters | |
| dc.subject.en | fatty acids | |
| dc.subject.en | RENEWABLE RESOURCES | |
| dc.title.en | Synthesis of Fatty Acid-Based Polyesters and Their Blends with Poly(L-lactide) as a Way To Tailor PLLA Toughness | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/sc500648g | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | ACS Sustainable Chemistry & Engineering | |
| bordeaux.page | 283-292 | |
| bordeaux.volume | 3 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 2 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01366390 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01366390v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS%20Sustainable%20Chemistry%20&%20Engineering&rft.date=2015&rft.volume=3&rft.issue=2&rft.spage=283-292&rft.epage=283-292&rft.eissn=2168-0485&rft.issn=2168-0485&rft.au=LEBARB%C3%89,%20Thomas&GRAU,%20Etienne&GADENNE,%20Beno%C3%AEt&ALFOS,%20Carine&CRAMAIL,%20Henri&rft.genre=article |
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