Bio-Based Aliphatic Polyurethanes Through ADMET Polymerization in Bulk and Green Solvent
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | LEBARBÉ, Thomas | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | MORE, Arvind S. | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | SANE, Prakash Sudhir | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | GRAU, Etienne
IDREF: 187909261 | |
| hal.structure.identifier | Institut des Corps Gras [ITERG] | |
| dc.contributor.author | ALFOS, Carine | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 1022-1336 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19777 | |
| dc.description.abstractEn | A new route to ,-diene urethane monomer is proposed by converting 10-undecenoic acid into the corresponding acyl azide, followed by urethanization with 10-undecenol. ADMET polymerizations of this ,-diene urethane monomer as well as other bio-based ,-dienes bearing various organic functions (ester, carbonate, ether, amide) were carried out in bulk and solution conditions. A screening of the most commonly used metathesis catalysts allows to evaluate their tolerance toward the urethane function as well as toward Polarclean, a green and nontoxic high boiling point solvent. The influence of the nature of the central organic function in these ,-diene monomers on the thermomechanical properties is investigated. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | ISOMERIZATION | |
| dc.subject.en | PLANT OILS | |
| dc.subject.en | METATHESIS | |
| dc.subject.en | ADMET | |
| dc.subject.en | Curtius rearrangement | |
| dc.subject.en | fatty acids | |
| dc.subject.en | polyurethane | |
| dc.subject.en | solution | |
| dc.subject.en | RENEWABLE RESOURCES | |
| dc.subject.en | CASTOR-OIL | |
| dc.subject.en | MIMICS | |
| dc.title.en | Bio-Based Aliphatic Polyurethanes Through ADMET Polymerization in Bulk and Green Solvent | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/marc.201300695 | |
| dc.subject.hal | Chimie/Polymères | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie | |
| bordeaux.journal | Macromolecular Rapid Communications | |
| bordeaux.page | 479-483 | |
| bordeaux.volume | 35 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 4 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01366323 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01366323v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2014&rft.volume=35&rft.issue=4&rft.spage=479-483&rft.epage=479-483&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=LEBARB%C3%89,%20Thomas&MORE,%20Arvind%20S.&SANE,%20Prakash%20Sudhir&GRAU,%20Etienne&ALFOS,%20Carine&rft.genre=article |
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