Core-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films
| dc.rights.license | open | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | ANTOINE, Ségolène | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | AISSOU, Karim | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | MUMTAZ, Muhammad | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | TELITEL, Siham | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | PECASTAINGS, Gilles | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | WIROTIUS, Anne-Laure | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | BROCHON, Cyril | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | FLEURY, Guillaume | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | HADZIIOANNOU, Georges | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2018 | |
| dc.identifier.issn | 1022-1336 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19644 | |
| dc.description.abstractEn | The synthesis and self-assembly in thin-film configuration of linear ABC triblock terpolymer chains consisting of polystyrene (PS), poly(2-vinylpyridine) (P2VP), and polyisoprene (PI) are described. For that purpose, a hydroxylterminated PS-b-P2VP (45 kg mol−1) building block and a carboxyl-terminated PI (9 kg mol−1) are first separately prepared by anionic polymerization, and then are coupled via a Steglich esterification reaction. This quantitative and metal-free catalyst synthesis route reveals to be very interesting since functionalization and purification steps are straightforward, and well-defined terpolymers are produced. A solvent vapor annealing (SVA) process is used to promote the self-assembly of frustrated PS-b-P2VP-b-PI chains into a thinfilm core–shell double gyroid (Q230, space group: Ia3d) structure. As terraces are formed within PS-b-P2VP-b-PI thin films during the SVA process under a CHCl3 vapor, different plane orientations of the Q230 structure ((211), (110), (111), and (100)) are observed at the polymer–air interface depending on the film thickness. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | self-assembly | |
| dc.subject.en | anionic polymerization | |
| dc.subject.en | core–shell double gyroid structure | |
| dc.subject.en | selfassembly | |
| dc.subject.en | Steglich esterification | |
| dc.subject.en | thin films | |
| dc.subject.en | Core-shell double gyroid structure | |
| dc.subject.en | thin film | |
| dc.title.en | Core-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/marc.201800043 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Rapid Communications | |
| bordeaux.page | 1800043 | |
| bordeaux.volume | 39 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 9 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01755261 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01755261v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Rapid%20Communications&rft.date=2018&rft.volume=39&rft.issue=9&rft.spage=1800043&rft.epage=1800043&rft.eissn=1022-1336&rft.issn=1022-1336&rft.au=ANTOINE,%20S%C3%A9gol%C3%A8ne&AISSOU,%20Karim&MUMTAZ,%20Muhammad&TELITEL,%20Siham&PECASTAINGS,%20Gilles&rft.genre=article |
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