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Post-functionalization of polyvinylcarbazoles: An open route towards hole transporting materials for perovskite solar cells

dc.rights.licenseopen
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorGEFFROY, Camille
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorGRANA, Eftychia
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorMUMTAZ, Muhammad
hal.structure.identifierResearch Center for Advanced Science and Technology [Tokyo] [RCAST]
dc.contributor.authorCOJOCARU, Ludmila
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorOLIVIER, Céline
hal.structure.identifierResearch Center for Advanced Science and Technology [Tokyo] [RCAST]
dc.contributor.authorUCHIDA, Satoshi
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTOUPANCE, Thierry
hal.structure.identifierResearch Center for Advanced Science and Technology [Tokyo] [RCAST]
dc.contributor.authorSEGAWA, Hiroshi
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2019
dc.identifier.issn0038-092X
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19640
dc.description.abstractEnWe report on the potential of tuning poly(9-vinylcarbazole) (PVK) properties through functionalization for an application as hole transport material (HTM) for perovskite solar cells (PSCs). The synthesized PVK-based polymers were substituted with moieties of interest to improve the solubility, the charge transport properties, or to tune energy levels. Bis(4-methoxyphenyl)amine moieties were found to improve the hole mobility and to increase the HOMO level of the PVK. Therefore, PSCs employing PVK-[N(PhOCH3)2]2 as HTM exhibited a best PCE of 16.7%. Compared to spiro-OMeTAD, first studies have shown that PVK-[N(PhOCH3)2]2 could extend PSC lifetime.
dc.language.isoen
dc.publisherElsevier
dc.subject.enPolyvinylcarbazoles
dc.subject.enHole-transporting materials
dc.subject.enPerovskite solar cells
dc.subject.enHole mobility
dc.subject.enDevice stability
dc.title.enPost-functionalization of polyvinylcarbazoles: An open route towards hole transporting materials for perovskite solar cells
dc.typeArticle de revue
dc.identifier.doi10.1016/j.solener.2019.10.034
dc.subject.halChimie/Polymères
bordeaux.journalSolar Energy
bordeaux.page878-884
bordeaux.volume193
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02330648
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02330648v1
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