Well-defined polyelectrolyte and its copolymers by reversible addition fragmentation chain transfer (RAFT) polymerization: Synthesis and applications
| dc.rights.license | open | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | MUMTAZ, Muhammad | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | AISSOU, Karim | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | KATSIGIANNOPOULOS, Dimitrios | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | BROCHON, Cyril | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| hal.structure.identifier | Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies | |
| dc.contributor.author | HADZIIOANNOU, Georges | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 2046-2069 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19620 | |
| dc.description.abstractEn | Reversible Addition-Fragmentation Chain Transfer (RAFT) polymerization of 4-styrenesulfonyl(trifluoromethylsulfonyl)imide potassium salt (SKTFSI) in N,N-dimethylformamide (DMF) solution was carried out using 2-(dodecylsulfanylthiocarbonylsulfanyl)-2-methylpropionic acid (DDMAT) as a reversible chain transfer agent in the presence of 2,2′-azobisisobutyronitrile (AIBN) at 65 °C in an inert atmosphere. We showed both homopolymers and well-defined polyelectrolyte diblock copolymer systems could be prepared through the direct polymerization of the charged SKTFSI monomer. To produce Li-ion polyelectrolytes, a cation exchange methodology (e.g. K+ → Li+) was used. Self-assembly of single-ion diblock copolymer thin films consisting of a Li-ion conductive PSLiTFSI block associated with a glassy polystyrene block is also demonstrated. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | RAFT polymerization | |
| dc.subject.en | polyelectrolyte | |
| dc.subject.en | block copolymer | |
| dc.subject.en | self-assembly | |
| dc.subject.en | thin film | |
| dc.title.en | Well-defined polyelectrolyte and its copolymers by reversible addition fragmentation chain transfer (RAFT) polymerization: Synthesis and applications | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/C5RA19730A | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | RSC Advances | |
| bordeaux.page | 98559-98565 | |
| bordeaux.volume | 5 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 119 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02922631 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02922631v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=RSC%20Advances&rft.date=2015&rft.volume=5&rft.issue=119&rft.spage=98559-98565&rft.epage=98559-98565&rft.eissn=2046-2069&rft.issn=2046-2069&rft.au=MUMTAZ,%20Muhammad&AISSOU,%20Karim&KATSIGIANNOPOULOS,%20Dimitrios&BROCHON,%20Cyril&CLOUTET,%20Eric&rft.genre=article |
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