Well-defined polyelectrolyte and its copolymers by reversible addition fragmentation chain transfer (RAFT) polymerization: Synthesis and applications
MUMTAZ, Muhammad
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
AISSOU, Karim
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
KATSIGIANNOPOULOS, Dimitrios
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
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Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
MUMTAZ, Muhammad
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
AISSOU, Karim
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
KATSIGIANNOPOULOS, Dimitrios
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
BROCHON, Cyril
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
CLOUTET, Eric
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
HADZIIOANNOU, Georges
Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
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Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
Language
en
Article de revue
This item was published in
RSC Advances. 2015, vol. 5, n° 119, p. 98559-98565
Royal Society of Chemistry
English Abstract
Reversible Addition-Fragmentation Chain Transfer (RAFT) polymerization of 4-styrenesulfonyl(trifluoromethylsulfonyl)imide potassium salt (SKTFSI) in N,N-dimethylformamide (DMF) solution was carried out using 2-(dodecylsu ...Read more >
Reversible Addition-Fragmentation Chain Transfer (RAFT) polymerization of 4-styrenesulfonyl(trifluoromethylsulfonyl)imide potassium salt (SKTFSI) in N,N-dimethylformamide (DMF) solution was carried out using 2-(dodecylsulfanylthiocarbonylsulfanyl)-2-methylpropionic acid (DDMAT) as a reversible chain transfer agent in the presence of 2,2′-azobisisobutyronitrile (AIBN) at 65 °C in an inert atmosphere. We showed both homopolymers and well-defined polyelectrolyte diblock copolymer systems could be prepared through the direct polymerization of the charged SKTFSI monomer. To produce Li-ion polyelectrolytes, a cation exchange methodology (e.g. K+ → Li+) was used. Self-assembly of single-ion diblock copolymer thin films consisting of a Li-ion conductive PSLiTFSI block associated with a glassy polystyrene block is also demonstrated.Read less <
English Keywords
RAFT polymerization
polyelectrolyte
block copolymer
self-assembly
thin film
Origin
Hal imported