Ring-opening polymerization of γ-lactones and copolymerization with other cyclic monomers
dc.rights.license | open | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
hal.structure.identifier | South China University of Technology [Guangzhou] [SCUT] | |
dc.contributor.author | SONG, Qilei | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | PASCOUAU, Chloé | |
hal.structure.identifier | South China University of Technology [Guangzhou] [SCUT] | |
dc.contributor.author | ZHAO, Junpeng | |
hal.structure.identifier | South China University of Technology [Guangzhou] [SCUT] | |
dc.contributor.author | ZHANG, Guangzhao | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
dc.contributor.author | CARLOTTI, Stéphane | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0079-6700 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19558 | |
dc.description.abstractEn | Triggered by raised environmental awareness and the rising requirements for sustainable polymers such as degradable or recyclable polymers, studies on ring-opening (co)polymerization (ROP/ROCP) of (bio-based) cyclic monomers (e.g., cyclic esters, lactides, epoxides etc.) have been booming in recent years. Renewable five-membered γ-butyrolactone (γBL) and derivatives would thus be a desirable feedstock to produce poly(γ-butyrolactone) (PγBL) and different (bio-based) functional polyesters. Their copolymerization with other cyclic monomers could also afford an alternative to tune the properties of the resulting materials. Although γBL was traditionally regarded "non-polymerizable", some progresses were made recently concerning the ROP/ROCP of γBL and derivatives. More importantly, some polyesters could be totally depolymerized back to their monomers by thermal or chemical treatment. This review is specially focused on ROP of γ-lactones and their copolymerization with other cyclic monomers by different catalytic/initiating systems, including Lewis/Brønsted acids, organic bases and alkali metal compounds, organometallic compounds, and cooperative bicomponent catalytic systems. The depolymerization process of some obtained polyesters is also discussed. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | γ-lactones | |
dc.subject.en | polyester | |
dc.subject.en | ring-opening (co)polymerization | |
dc.subject.en | sustainable polymer | |
dc.title.en | Ring-opening polymerization of γ-lactones and copolymerization with other cyclic monomers | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.progpolymsci.2020.101309 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Progress in Polymer Science | |
bordeaux.page | 101309 | |
bordeaux.volume | 110 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-02953317 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-02953317v1 | |
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