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Influence of synthesis parameters on the short-range structure and electrochemical performances of Li2MnO2F

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDEVILLE, Quentin
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
hal.structure.identifierSAFT [Bordeaux]
dc.contributor.authorWERNERT, Romain
hal.structure.identifierSAFT [Bordeaux]
dc.contributor.authorDILLAY, Valérie
hal.structure.identifierSAFT [Bordeaux]
dc.contributor.authorMORTEMARD DE BOISSE, Benoît
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorGUIGNARD, Marie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
hal.structure.identifierAdvanced Lithium Energy Storage Systems - ALISTORE-ERI [ALISTORE-ERI]
dc.contributor.authorCARLIER, Dany
dc.date.issued2024
dc.identifier.issn0020-1669
dc.description.abstractEnIn the last years, disordered rocksalt structure (DRS) materials were proposed as a positive electrode for lithium-ion batteries. In particular, the fluorinated DRS materials were proposed to be more stable upon cycling than pure oxide counterparts. These materials are mainly obtained by mechanosynthesis in order to incorporate a significant number of F ions and maintain a disordered structure. Since the local structural arrangement is crucial for battery application, we aim to monitor its evolution upon the synthesis of Li2MnO2F from two sets of precursors: Mn2O3, Li2O, and LiF or LiMnO2 and LiF. The synthesis progress was thus followed, by 7Li and 19F MAS NMR coupled to XRD to probe the structure at different scales. This allowed us to identify an optimal milling time to reach the final compounds. We show that they exhibit similar morphology (by SEM), medium- and short-range orders (by XRD, 7Li and 19F NMR, EXAFS), and average Mn oxidation degree (by XANES). The electrochemical performances of the two compounds are almost similar, with high specific capacities of 319 mAh·g–1 (“from LiMnO2”) and 304 mAh·g–1 (“from Mn2O3”) for the first charge to 4.8 V vs Li+/Li, proving their interest as post-NMC candidates as positive electrode materials.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enLi-ion batteries
dc.subject.enPositive electrode material
dc.subject.enDisordered rocksalt
dc.subject.enOxyfluoride
dc.subject.enMAS-NMR
dc.subject.enOxygen redox
dc.title.enInfluence of synthesis parameters on the short-range structure and electrochemical performances of Li2MnO2F
dc.typeArticle de revue
dc.identifier.doi10.1021/acs.inorgchem.3c03863
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page5341-5350
bordeaux.volume63
bordeaux.issue12
bordeaux.peerReviewedoui
hal.identifierhal-04520558
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-04520558v1
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