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Secondary Organic Aerosol Formation from Aromatic Alkene Ozonolysis: Influence of the Precursor Structure on Yield, Chemical Composition, and Mechanism

dc.rights.licenseopenen_US
hal.structure.identifierLaboratoire Interuniversitaire des Systèmes Atmosphériques [LISA (UMR_7583)]
dc.contributor.authorCHIAPPINI, Laura
hal.structure.identifierLaboratoire Interuniversitaire des Systèmes Atmosphériques [LISA (UMR_7583)]
hal.structure.identifierEnvironnements et Paléoenvironnements OCéaniques [EPOC]
dc.contributor.authorPERRAUDIN, Emilie
hal.structure.identifierLaboratoire Interuniversitaire des Systèmes Atmosphériques [LISA (UMR_7583)]
dc.contributor.authorMAURIN, Nicolas
hal.structure.identifierLaboratoire Interuniversitaire des Systèmes Atmosphériques [LISA (UMR_7583)]
dc.contributor.authorPICQUET-VARRAULT, Benedicte
hal.structure.identifierLaboratoire Chimie de l'environnement [LCE]
dc.contributor.authorZHENG, Wuyin
hal.structure.identifierLaboratoire Chimie de l'environnement [LCE]
dc.contributor.authorMARCHAND, Nicolas
hal.structure.identifierLaboratoire Chimie de l'environnement [LCE]
dc.contributor.authorTEMIME-ROUSSEL, Brice
hal.structure.identifierLaboratoire Chimie de l'environnement [LCE]
dc.contributor.authorMONOD, Anne
hal.structure.identifierLaboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
hal.structure.identifierInstitut de Combustion, Aérothermique, Réactivité et Environnement [ICARE]
dc.contributor.authorLE PERSON, Annaïg
hal.structure.identifierInstitut de Combustion, Aérothermique, Réactivité et Environnement [ICARE]
dc.contributor.authorBERNARD, François
hal.structure.identifierLaboratoire Chimie de l'environnement [LCE]
dc.contributor.authorEYGLUNENT, Grégory
hal.structure.identifierInstitut de Combustion, Aérothermique, Réactivité et Environnement [ICARE]
dc.contributor.authorMELLOUKI, Abdelwahid
hal.structure.identifierLaboratoire Interuniversitaire des Systèmes Atmosphériques [LISA (UMR_7583)]
dc.contributor.authorDOUSSIN, Jean-François
dc.date.accessioned2024-02-28T08:40:52Z
dc.date.available2024-02-28T08:40:52Z
dc.date.issued2019
dc.identifier.issn1089-5639en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/188474
dc.description.abstractEnThe influence of the precursor chemical structure on secondary organic aerosol (SOA) formation was investigated through the study of the ozonolysis of two anthropogenic aromatic alkenes: 2-methylstyrene and indene. Experiments were carried out in three different simulation chambers: ICARE 7300L FEP Teflon chamber (ICARE, Orléans, France), EUPHORE FEP Teflon chamber (CEAM, Valencia, Spain), and CESAM evacuable stainless steel chamber (LISA, Créteil, France). For both precursors, SOA yield and growth were studied on a large range of initial concentrations (from ∼60 ppbv to 1.9 ppmv) and the chemical composition of both gaseous and particulate phases was investigated at a molecular level. Gas phase was described using FTIR spectroscopy and online gas chromatography coupled to mass spectrometry, and particulate chemical composition was analyzed (i) online by thermo-desorption coupled to chemical ionization mass spectrometry and (ii) offline by supercritical fluid extraction coupled to gas chromatography and mass spectrometry. The results obtained from a large set of experiments performed in three different chambers and using several complementary analytical techniques were in very good agreement. SOA yield was up to 10 times higher for indene ozonolysis than for 2-methylstyrene ozonolysis at the same reaction advancement. For 2-methylstyrene ozonolysis, formaldehyde and o-tolualdehyde were the two main gaseous phase products while o-toluic acid was the most abundant among six products detected within the particulate phase. For indene ozonolysis, traces of formic and phthalic acids as well as 11 species were detected in the gaseous phase and 11 other products were quantified in the particulate phase, where phthaldialdehyde was the main product. On the basis of the identified products, reaction mechanisms were proposed that highlight specific pathways due to the precursor chemical structure. These mechanisms were finally compared and discussed regarding SOA formation. In the case of 2-methylstyrene ozonolysis, ozone adds mainly on the external and monosubstituted double bond, yielding only one C8- and monofunctionalized Criegee intermediate and hence more volatile products as well as lower SOA mass than indene ozonolysis in similar experimental conditions. In the case of indene, ozone adds mainly on the five-carbon-ring and disubstituted C═C double bond, leading to the formation of two C9- and bifunctionalized Criegee intermediates, which then evolve via different pathways including the hydroperoxide channel and form highly condensable first-generation products.
dc.language.isoENen_US
dc.title.enSecondary Organic Aerosol Formation from Aromatic Alkene Ozonolysis: Influence of the Precursor Structure on Yield, Chemical Composition, and Mechanism
dc.typeArticle de revueen_US
dc.identifier.doi10.1021/acs.jpca.8b10394en_US
dc.subject.halChimie/Autreen_US
dc.subject.halChimie/Chimie théorique et/ou physiqueen_US
dc.subject.halSciences de l'environnementen_US
bordeaux.journalJournal of Physical Chemistry Aen_US
bordeaux.page1469-1484en_US
bordeaux.volume123en_US
bordeaux.hal.laboratoriesEPOC : Environnements et Paléoenvironnements Océaniques et Continentaux - UMR 5805en_US
bordeaux.issue7en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionCNRSen_US
bordeaux.teamLPTCen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcehal
hal.identifierhal-02067818
hal.version1
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Physical%20Chemistry%20A&rft.date=2019&rft.volume=123&rft.issue=7&rft.spage=1469-1484&rft.epage=1469-1484&rft.eissn=1089-5639&rft.issn=1089-5639&rft.au=CHIAPPINI,%20Laura&PERRAUDIN,%20Emilie&MAURIN,%20Nicolas&PICQUET-VARRAULT,%20Benedicte&ZHENG,%20Wuyin&rft.genre=article


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