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A new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid

hal.structure.identifierInstitut des Matériaux de Nantes Jean Rouxel [IMN]
dc.contributor.authorAMIAUD, Thibault
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJUBERA, Véronique
hal.structure.identifierInstitut des Matériaux de Nantes Jean Rouxel [IMN]
dc.contributor.authorSERIER-BRAULT, Hélène
dc.date.issued2023
dc.identifier.issn2050-7526
dc.description.abstractEnA ratiometric thermometer based on a mixed Eu-Tb metal-organic framework is reported with a maximum relative thermal sensitivity of 16.1% K-1 at 11 K making this material one of the best-performing thermometers currently reported in the literature. The sensing mechanism of {[Tb2-xEux(H(2)Btec)(Btec)(H2O)(2)]& BULL;4H(2)O}(n) (Btec = 1,2,4,5 Benzenetetracarboxylic acid) has been attributed to a phonon-assisted energy migration between neighboring Tb3+ ions in the structure.
dc.description.sponsorshipMOFs à base de lanthanides pour une application de nanothermomètres luminescents - ANR-18-CE09-0008
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enA new highly sensitive cryogenic luminescent MOF thermometer built with pyromellitic acid
dc.typeArticle de revue
dc.identifier.doi10.1039/d3tc02125d
dc.subject.halChimie/Matériaux
dc.subject.halPhysique [physics]/Physique [physics]/Instrumentations et Détecteurs [physics.ins-det]
bordeaux.journalJournal of Materials Chemistry C
bordeaux.page10951-10956
bordeaux.volume11
bordeaux.issue32
bordeaux.peerReviewedoui
hal.identifierhal-04182580
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-04182580v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Materials%20Chemistry%20C&rft.date=2023&rft.volume=11&rft.issue=32&rft.spage=10951-10956&rft.epage=10951-10956&rft.eissn=2050-7526&rft.issn=2050-7526&rft.au=AMIAUD,%20Thibault&JUBERA,%20V%C3%A9ronique&SERIER-BRAULT,%20H%C3%A9l%C3%A8ne&rft.genre=article


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