Phase transitions and chemical transformations of nitromethane up to 350 °C and 35 GPa
| hal.structure.identifier | Centre d'Etudes de Vaujours-Moronvilliers | |
| dc.contributor.author | COURTECUISSE, Stéphane | |
| hal.structure.identifier | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP] | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CANSELL, François | |
| hal.structure.identifier | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP] | |
| dc.contributor.author | FABRE, Denise | |
| hal.structure.identifier | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP] | |
| dc.contributor.author | PETITET, Jean-Pierre | |
| dc.date.issued | 1995 | |
| dc.identifier.issn | 0021-9606 | |
| dc.description.abstractEn | Nitromethane has been studied as a model of the energetic nitro compounds. The phase diagram has been determined by Raman scattering in the pressure and temperature ranges of 0–35 GPa and 20–350 °C, respectively. Three new solid phases of nitromethane called III, IV, V, and their domain of stability have been located. A first chemical transformation is observed by the disappearance of nitromethane Raman modes and by the irreversible formation of a transparent solid called compound I (CI). A second chemical transformation [compound I–compound II (CII)], at higher temperature than the first one, is observed by the sudden darkening of the sample. | |
| dc.language.iso | en | |
| dc.publisher | American Institute of Physics | |
| dc.title.en | Phase transitions and chemical transformations of nitromethane up to 350 °C and 35 GPa | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1063/1.469165 | |
| dc.subject.hal | Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph] | |
| bordeaux.journal | Journal of Chemical Physics | |
| bordeaux.page | 968 - 974 | |
| bordeaux.volume | 102 | |
| bordeaux.issue | 2 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-04205359 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-04205359v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Chemical%20Physics&rft.date=1995&rft.volume=102&rft.issue=2&rft.spage=968%20-%20974&rft.epage=968%20-%20974&rft.eissn=0021-9606&rft.issn=0021-9606&rft.au=COURTECUISSE,%20St%C3%A9phane&CANSELL,%20Fran%C3%A7ois&FABRE,%20Denise&PETITET,%20Jean-Pierre&rft.genre=article |
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