Phase transitions and chemical transformations of nitromethane up to 350 °C and 35 GPa
CANSELL, François
Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
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Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
CANSELL, François
Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
< Reduce
Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Language
en
Article de revue
This item was published in
Journal of Chemical Physics. 1995, vol. 102, n° 2, p. 968 - 974
American Institute of Physics
English Abstract
Nitromethane has been studied as a model of the energetic nitro compounds. The phase diagram has been determined by Raman scattering in the pressure and temperature ranges of 0–35 GPa and 20–350 °C, respectively. Three new ...Read more >
Nitromethane has been studied as a model of the energetic nitro compounds. The phase diagram has been determined by Raman scattering in the pressure and temperature ranges of 0–35 GPa and 20–350 °C, respectively. Three new solid phases of nitromethane called III, IV, V, and their domain of stability have been located. A first chemical transformation is observed by the disappearance of nitromethane Raman modes and by the irreversible formation of a transparent solid called compound I (CI). A second chemical transformation [compound I–compound II (CII)], at higher temperature than the first one, is observed by the sudden darkening of the sample.Read less <
Origin
Hal imported