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Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb( iii ) single-molecule magnets

hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorMATTEI, Carlo Andrea
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorMONTIGAUD, Vincent
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorLEFEUVRE, Bertrand
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorDORCET, Vincent
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorARGOUARCH, Gilles
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorCADOR, Olivier
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorLE GUENNIC, Boris
hal.structure.identifierLaboratoire de Chimie - UMR5182 [LC]
dc.contributor.authorMAURY, Olivier
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorLALLI, Claudia
hal.structure.identifieriLM - Luminescence [iLM - LUMINESCENCE]
dc.contributor.authorGUYOT, Yannick
hal.structure.identifieriLM - Matériaux et nanostructures photoniques [iLM - MNP]
dc.contributor.authorGUY, Stéphan
hal.structure.identifieriLM - Matériaux et nanostructures photoniques [iLM - MNP]
dc.contributor.authorGINDRE, Cyprien
hal.structure.identifieriLM - Matériaux et nanostructures photoniques [iLM - MNP]
dc.contributor.authorBENSALAH-LEDOUX, Amina
hal.structure.identifierLaboratoire de Chimie - UMR5182 [LC]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorRIOBÉ, François
hal.structure.identifieriLM - Matériaux et nanostructures photoniques [iLM - MNP]
dc.contributor.authorBAGUENARD, Bruno
hal.structure.identifierInstitut des Sciences Chimiques de Rennes [ISCR]
dc.contributor.authorPOINTILLART, Fabrice
dc.date.issued2023
dc.identifier.issn2050-7526
dc.description.abstractEnLanthanide ions have attracted great interest owing to their optical and magnetic properties. Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years. Moreover, chiral lanthanide complexes allow the observation of remarkable circularly polarized luminescence (CPL). However, the combination of both SMM and CPL behaviors in a single molecular system is very rare and deserves attention in the design of multifunctional materials. Four chiral one-dimensional coordination compounds involving 1,1′-Bi-2-naphtol (BINOL)-derived bisphosphate ligands and the Yb(III) centre were synthesized and characterized by powder and single-crystal X-ray diffraction. All the Yb(III)-based polymers displayed field-induced SMM behavior with magnetic relaxation occurring by applying Raman processes and near infrared CPL in the solid state.
dc.description.sponsorshipLuminescence polarisée circulairement de molécules-aimants à base de lanthanide - ANR-19-CE29-0012
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.rights.urihttp://creativecommons.org/licenses/by-nc/
dc.title.enCircularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb( iii ) single-molecule magnets
dc.typeArticle de revue
dc.identifier.doi10.1039/d3tc00858d
dc.subject.halChimie/Chimie de coordination
dc.subject.halChimie/Chimie théorique et/ou physique
dc.description.sponsorshipEuropeMULtiple PROperties Single Molecule Magnets
bordeaux.journalJournal of Materials Chemistry C
bordeaux.page7299-7310
bordeaux.volume11
bordeaux.issue22
bordeaux.peerReviewedoui
hal.identifierhal-04127855
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-04127855v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Materials%20Chemistry%20C&rft.date=2023&rft.volume=11&rft.issue=22&rft.spage=7299-7310&rft.epage=7299-7310&rft.eissn=2050-7526&rft.issn=2050-7526&rft.au=MATTEI,%20Carlo%20Andrea&MONTIGAUD,%20Vincent&LEFEUVRE,%20Bertrand&DORCET,%20Vincent&ARGOUARCH,%20Gilles&rft.genre=article


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