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Photo-crystallography: from the structure towards the electron density of metastable states

hal.structure.identifierCristallographie, Résonance Magnétique et Modélisations [CRM2]
hal.structure.identifierLaboratoire de Cristallographie et modélisation des matériaux minéraux et biologiques [LCM3B]
dc.contributor.authorLEGRAND, V.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARBONERA, Chiara
hal.structure.identifierLaboratoire de Cristallographie et modélisation des matériaux minéraux et biologiques [LCM3B]
hal.structure.identifierCristallographie, Résonance Magnétique et Modélisations [CRM2]
dc.contributor.authorPILLET, Sébastien
hal.structure.identifierCristallographie, Résonance Magnétique et Modélisations [CRM2]
hal.structure.identifierLaboratoire de Cristallographie et modélisation des matériaux minéraux et biologiques [LCM3B]
dc.contributor.authorSOUHASSOU, Mohamed
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierCristallographie, Résonance Magnétique et Modélisations [CRM2]
hal.structure.identifierLaboratoire de Cristallographie et modélisation des matériaux minéraux et biologiques [LCM3B]
dc.contributor.authorLECOMTE, Claude
dc.date.issued2005-01-01
dc.identifier.issn1742-6596
dc.description.abstractEnA photo-crystallographic study of Fe(btr)2(NCS)2 H2O was performed in order to describe the modification of structures and charge densities on going from the ground low spin (LS) state to the metastable high spin (HS) state during the LIESST phenomenon at 15 K. Related photo-magnetic and spectroscopic measurements are also described. We show that at 15 K, the thermally quenched and photo-induced structures of the metastable HS state are identical. For comparison, we also derived the structure of the HS and LS states at 130 K in the hysteresis loop; the thermal spin transition and the LIESST spin transition exhibit similar structural behaviours.
dc.language.isoen
dc.publisherIOP Science
dc.rights.urihttp://creativecommons.org/licenses/by/
dc.title.enPhoto-crystallography: from the structure towards the electron density of metastable states
dc.typeArticle de revue
dc.identifier.doi10.1088/1742-6596/21/1/012
dc.subject.halSciences de l'ingénieur [physics]/Mécanique [physics.med-ph]
dc.subject.halSciences de l'ingénieur [physics]/Matériaux
bordeaux.journalJournal of Physics: Conference Series
bordeaux.page73 - 80
bordeaux.volume21
bordeaux.peerReviewedoui
hal.identifierhal-01007183
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01007183v1
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