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hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorOBERLE, J.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorABRAHAM, Emmanuel
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorIVANOV, A.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorJONUSAUSKAS, Gediminas
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorRULLIERE, C.
dc.date.issued1997-05-30
dc.identifier.issn1010-6030
dc.description.abstractEnWe report the direct observation of the formation and stabilization of the radical cation of 1,4-diphenylbutadiene (DPB) in polar solvents (acetonitrile, linear alcohols) by picosecond “pump-probe” and polarization-sensitive resonant CARS (Coherent Anti-Stokes Raman Scattering) experiments. For the first time, we have observed the formation and stabilization rate of the DPB radical cation which occurs on a 10–20 ps timescale. We confirm that the formation process is mainly monophotonic.
dc.language.isoen
dc.publisherElsevier
dc.subject.enCARS
dc.subject.enCation formation
dc.subject.enDiphenylpolyenes
dc.subject.enExcited states
dc.subject.enFemtosecond
dc.subject.enNon-linear optics
dc.subject.enTransient absorption
dc.subject.enVibrational spectroscopy
dc.title.enPicosecond photoinduced formation of a radical cation: CARS and transient absorption studies of 1,4-diphenylbutadiene
dc.typeArticle de revue
dc.identifier.doi10.1016/S1010-6030(96)04545-5
dc.subject.halPhysique [physics]
dc.subject.halPhysique [physics]/Physique [physics]/Optique [physics.optics]
bordeaux.journalJournal of Photochemistry and Photobiology A: Chemistry
bordeaux.page217-223
bordeaux.volume105
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-01550084
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01550084v1
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