Picosecond observation of cation-stepwise delayed and cation-triggered photoinduced intramolecular charge transfer in fluorescent cation probes
| hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
| dc.contributor.author | JONUSAUSKAS, Gediminas | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LAPOUYADE, R. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DELMOND, S. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LETARD, J. F. | |
| hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
| dc.contributor.author | RULLIERE, C. | |
| dc.date.issued | 1996-10 | |
| dc.identifier.issn | 0021-7689 | |
| dc.description.abstractEn | Time-resolved transient absorption and gain spectra with subpicosecond laser excitation are reported for donor-donor and acceptor-donor stilbene-crowns (in each compound the electron donor group is the 15-aza-5-crown macrocycle, D<sub>1<sub/>). The effect of the calcium cation on the photoinduced intramolecular charge transfer (ICT) rate constants are measured. When the cation is on the donor side of the molecular system (class 1: D<sub>1<sub/>CS-Crown), the photoinduced ICT process is slowed down and goes through several intermediates characterized by a distancing of the cation, while a solvent molecule enters its coordination sphere. When the cation is on the acceptor side (class 2: D<sub>1<sub/>DS-Crown,D<sub>1<sub/>DB-Crown and D<sub>1<sub/>DCS-Crown), the photoinduced ICT process becomes too fast to be measured, even on the picosecond scale. | |
| dc.language.iso | en | |
| dc.publisher | EDP Sciences | |
| dc.title.en | Picosecond observation of cation-stepwise delayed and cation-triggered photoinduced intramolecular charge transfer in fluorescent cation probes | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1051/jcp/1996931670 | |
| dc.subject.hal | Physique [physics] | |
| dc.subject.hal | Physique [physics]/Physique [physics]/Optique [physics.optics] | |
| bordeaux.journal | Journal de Chimie Physique et de Physico-Chimie Biologique | |
| bordeaux.page | 1670-1696 | |
| bordeaux.volume | 93 | |
| bordeaux.issue | 10 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01550085 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01550085v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20de%20Chimie%20Physique%20et%20de%20Physico-Chimie%20Biologique&rft.date=1996-10&rft.volume=93&rft.issue=10&rft.spage=1670-1696&rft.epage=1670-1696&rft.eissn=0021-7689&rft.issn=0021-7689&rft.au=JONUSAUSKAS,%20Gediminas&LAPOUYADE,%20R.&DELMOND,%20S.&LETARD,%20J.%20F.&RULLIERE,%20C.&rft.genre=article |
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