Polymorphism of cyclopentanol: Crystallographic characterization of the ordered and disordered phases
hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
dc.contributor.author | RUTE, M. A. | |
hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
dc.contributor.author | SALUD, Josep | |
hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
dc.contributor.author | LOPEZ, David O. | |
hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
dc.contributor.author | TAMARIT, Josep Lluis | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | NÉGRIER, Philippe | |
hal.structure.identifier | Departament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB] | |
dc.contributor.author | BARRIO, Maria | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | MONDIEIG, Denise | |
dc.date.created | 2003-05-19 | |
dc.date.issued | 2003 | |
dc.identifier.issn | 0897-4756 | |
dc.description.abstractEn | The polymorphism of cyclopentanol (C5H10O) has been further investigated by X-ray powder diffraction experiments and it has been found to agree with the most recent thermodynamic study [J. Chem. Thermodyn. 1995, 27, 953]. In addition to the previously reported orientationally disordered hexagonal phases I and II, the lattice symmetry of the low-temperature ordered phases III and IV have been determined by means of pattern-matching analyses both as monoclinic with Z = 24 (Cc and C2/c, respectively). The patterns revealed no significant differences between phases III and IV and the transition between both phases was found through careful determination of the variation of the lattice parameters as a function of the temperature. The strength of intermolecular interactions as well as the anisotropy in the solid phases has been analyzed by the study of the isobaric thermal-expansion tensor and the results are discussed in the light of previously reported literature covering dynamics disorder. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.rights.uri | http://creativecommons.org/licenses/by-sa/ | |
dc.title.en | Polymorphism of cyclopentanol: Crystallographic characterization of the ordered and disordered phases | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/cm031081b | |
dc.subject.hal | Physique [physics]/Matière Condensée [cond-mat] | |
dc.subject.hal | Chimie/Cristallographie | |
bordeaux.journal | Chemistry of Materials | |
bordeaux.page | 4725-4731 | |
bordeaux.volume | 15 | |
bordeaux.issue | 25 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01550888 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01550888v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20of%20Materials&rft.date=2003&rft.volume=15&rft.issue=25&rft.spage=4725-4731&rft.epage=4725-4731&rft.eissn=0897-4756&rft.issn=0897-4756&rft.au=RUTE,%20M.%20A.&SALUD,%20Josep&LOPEZ,%20David%20O.&TAMARIT,%20Josep%20Lluis&N%C3%89GRIER,%20Philippe&rft.genre=article |
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