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dc.contributor.authorMALLO, Neil
hal.structure.identifierUniversity of Cambridge [UK] [CAM]
dc.contributor.authorTRON, Arnaud
dc.contributor.authorANDRÉASSON, Joakim
dc.contributor.authorJACOB, Lorrie
dc.contributor.authorHARPER, Jason
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorMCCLENAGHAN, Nathan
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorJONUSAUSKAS, Gediminas
dc.contributor.authorBEVES, Jonathon Edward
dc.date.issued2020-06
dc.description.abstractEnThe binding of donor-acceptor Stenhouse adducts (DASAs) bearing hydrogenbond recognition groups by Hamilton-type receptors significantly influenced their photoswitching properties by altering thermal barriers to isomerization. The thermal barrier between the most stable linear isomer and the photo-generated isomer is lowered on binding to a receptor, and this barrier is crucial for switching properties. The thermal isomerization was shown to proceed via a stepwise linear-enol-keto mechanism in DMSO where the barrier to tautomerisation is within 2 kJ•mol-1 of that of the rate-determining step, which may be important for analyzing switching properties.
dc.language.isoen
dc.publisherWiley
dc.title.enHydrogen‐bonding donor‐acceptor Stenhouse adducts
dc.typeArticle de revue
dc.identifier.doi10.1002/cptc.201900295
dc.subject.halPhysique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
dc.subject.halPhysique [physics]/Physique [physics]/Optique [physics.optics]
bordeaux.journalChemPhotoChem
bordeaux.peerReviewedoui
hal.identifierhal-02464386
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02464386v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ChemPhotoChem&rft.date=2020-06&rft.au=MALLO,%20Neil&TRON,%20Arnaud&ANDR%C3%89ASSON,%20Joakim&JACOB,%20Lorrie&HARPER,%20Jason&rft.genre=article


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