Hydrogen‐bonding donor‐acceptor Stenhouse adducts
dc.contributor.author | MALLO, Neil | |
hal.structure.identifier | University of Cambridge [UK] [CAM] | |
dc.contributor.author | TRON, Arnaud | |
dc.contributor.author | ANDRÉASSON, Joakim | |
dc.contributor.author | JACOB, Lorrie | |
dc.contributor.author | HARPER, Jason | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | MCCLENAGHAN, Nathan | |
hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
dc.contributor.author | JONUSAUSKAS, Gediminas | |
dc.contributor.author | BEVES, Jonathon Edward | |
dc.date.issued | 2020-06 | |
dc.description.abstractEn | The binding of donor-acceptor Stenhouse adducts (DASAs) bearing hydrogenbond recognition groups by Hamilton-type receptors significantly influenced their photoswitching properties by altering thermal barriers to isomerization. The thermal barrier between the most stable linear isomer and the photo-generated isomer is lowered on binding to a receptor, and this barrier is crucial for switching properties. The thermal isomerization was shown to proceed via a stepwise linear-enol-keto mechanism in DMSO where the barrier to tautomerisation is within 2 kJ•mol-1 of that of the rate-determining step, which may be important for analyzing switching properties. | |
dc.language.iso | en | |
dc.publisher | Wiley | |
dc.title.en | Hydrogen‐bonding donor‐acceptor Stenhouse adducts | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/cptc.201900295 | |
dc.subject.hal | Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph] | |
dc.subject.hal | Physique [physics]/Physique [physics]/Optique [physics.optics] | |
bordeaux.journal | ChemPhotoChem | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-02464386 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-02464386v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ChemPhotoChem&rft.date=2020-06&rft.au=MALLO,%20Neil&TRON,%20Arnaud&ANDR%C3%89ASSON,%20Joakim&JACOB,%20Lorrie&HARPER,%20Jason&rft.genre=article |
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