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hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorPANCHENKO, Pavel A.
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorFEDOROV, Yuri V.
hal.structure.identifierA. N. Nesmeyanov Institute of Organoelement Compounds [INEOS]
dc.contributor.authorFEDOROVA, Olga A.
hal.structure.identifierMendeleev University of Chemical Technology of Russia
dc.contributor.authorPEREVALOV, Valeri P.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorJONUSAUSKAS, Gediminas
dc.date.created2008-11-27
dc.date.issued2009-06
dc.identifier.issn1066-5285
dc.description.abstractEnA method for the synthesis of N-aryl-substituted 4 amino- and 4-acetylaminonaphthalimide derivatives with mono- and dialkoxy groups or a 15-crow-5 moiety in the N-aryl substituent is described. The introduction of electron-donating alkoxy groups into the benzene ring of the N-aryl fragment results in fluorescence quenching of the naphthalimide chromophore, which is most pronounced in the spectra of N-acetyl derivatives. The photophysical properties of the synthesized 4-amino- and 4-acetylaminonaphthalimides depend on the solvent polarity and its specific solvating ability due to H-bonding. The crown containing compounds are promising fluorescent chemosensors for metal cations.
dc.language.isoen
dc.publisherSpringer Verlag
dc.subject.ennaphthalimide
dc.subject.en15-crown-5
dc.subject.enfluorescence
dc.subject.enhydrogen bond
dc.subject.enUV-Vis absorption spectra
dc.subject.enfluorescent sensors
dc.subject.en4-nitronaphthalic anhydride
dc.subject.enphotoinduced charge transfer
dc.title.enSynthesis and spectral properties of 4-amino- and 4-acetylamino-N-arylnaphthalimides containing electron-donating groups in the N-aryl substituent
dc.typeArticle de revue
dc.identifier.doi10.1007/s11172-009-0160-x
dc.subject.halPhysique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
bordeaux.journalRussian Chemical Bulletin
bordeaux.page1199–1206
bordeaux.volume58
bordeaux.issue6
bordeaux.peerReviewedoui
hal.identifierhal-00506414
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00506414v1
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