Diameter-Dependent Solubility of Single-Walled Carbon Nanotubes
hal.structure.identifier | Department of Chemical and Biomolecular Engineering | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
hal.structure.identifier | Physical Chemistry and Applied Spectroscopy Group [C-PCS] | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | DUQUE, Juan G. | |
hal.structure.identifier | Department of Chemical and Biomolecular Engineering | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | PARRA-VASQUEZ, A. Nicholas G. | |
hal.structure.identifier | Department of Chemical and Biomolecular Engineering | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
dc.contributor.author | BEHABTU, Natnael | |
hal.structure.identifier | Department of Chemical and Biomolecular Engineering | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
hal.structure.identifier | Physical Chemistry and Applied Spectroscopy Group [C-PCS] | |
dc.contributor.author | GREEN MICAH, J. | |
hal.structure.identifier | Department of Chemistry | |
dc.contributor.author | HIGGINBOTHAM, Amanda L. | |
hal.structure.identifier | Department of Chemistry | |
dc.contributor.author | PRICE, B. Katherine | |
hal.structure.identifier | Department of Chemistry | |
dc.contributor.author | LEORNARD, Ashley D. | |
hal.structure.identifier | Department of Chemical and Biomolecular Engineering | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
hal.structure.identifier | Saudi Aramco | |
dc.contributor.author | SCHMIDT, Howard K. | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | LOUNIS, Brahim | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
hal.structure.identifier | Department of Chemistry | |
dc.contributor.author | TOUR, James M. | |
hal.structure.identifier | Physical Chemistry and Applied Spectroscopy Group [C-PCS] | |
dc.contributor.author | DOORN, Stephen K. | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | COGNET, Laurent | |
hal.structure.identifier | Department of Chemical and Biomolecular Engineering | |
hal.structure.identifier | The Smalley Institute for Nanoscale Science and Technology | |
hal.structure.identifier | Department of Chemistry | |
dc.contributor.author | PASQUALI, Matteo | |
dc.date.created | 2010-01-27 | |
dc.date.issued | 2010-06-22 | |
dc.identifier.issn | 1936-0851 | |
dc.description.abstractEn | We study the solubility and dispersibility of as-produced and purified HiPco single-walled carbon nanotubes (SWNTs). Variation in specific operating conditions of the HiPco process are found to lead to significant differences in the respective SWNT solubilities in oleum and surfactant suspensions. The diameter distributions of SWNTs dispersed in surfactant solutions are batch-dependent, as evidenced by luminescence and Raman spectroscopies, but are identical for metallic and semiconducting SWNTs within a batch. We thus find that small diameter SWNTs disperse at higher concentration in aqueous surfactants and dissolve at higher concentration in oleum than do large-diameter SWNTs. These results highlight the importance of controlling SWNT synthesis methods in order to optimize processes dependent on solubility, including macroscopic processing such as fiber spinning, material reinforcement, and films production, as well as for fundamental research in type selective chemistry, optoelectronics, and nanophotonics. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | single-walled carbon nanotubes | |
dc.subject.en | solubility | |
dc.subject.en | solutions | |
dc.subject.en | dispersions | |
dc.subject.en | diameter | |
dc.title.en | Diameter-Dependent Solubility of Single-Walled Carbon Nanotubes | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/nn100170f | |
bordeaux.journal | ACS Nano | |
bordeaux.page | 3063-3072 | |
bordeaux.volume | 4 | |
bordeaux.issue | 6 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00609610 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00609610v1 | |
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